Soot Oxidation in a Plasma-Catalytic Reactor: A Case Study of Zeolite-Supported Vanadium Catalysts

The plasma-catalytic oxidation of soot was studied over zeolite-supported vanadium catalysts, while four types of zeolites (MCM-41, mordenite, USY and 5A) were used as catalyst supports. The soot oxidation rate followed the order of V/MCM-41 > V/mordenite > V/USY > V/5A, while 100% soot oxidation was achieved at 54th min of reaction over V/MCM-41 and V/mordenite. The CO2 selectivity of the process follows the opposite order of oxidation rate over the V/M catalyst. A wide range of catalyst characterizations including N-2 adsorption-desorption, XRD, XPS, H-2-TPR and O-2-TPD were performed to obtain insights regarding the reaction mechanisms of soot oxidation in plasma-catalytic systems. The redox properties were recognized to be crucial for the soot oxidation process. The effects of discharge power, gas flow rate and reaction temperature on soot oxidation were also investigated. The results showed that higher discharge power, higher gas flow rate and lower reaction temperature were beneficial for soot oxidation rate. However, these factors would impose a negative effect on CO2 selectivity. The proposed plasma-catalysis method possessed the unique advantages of quick response, mild operation conditions and system compactness. The method could be potentially applied for the regeneration of diesel particulate filters (DPF) at low temperatures and contribute to the the emission control of diesel engines.

Automated summary

The plasma-catalytic oxidation of soot over zeolite-supported vanadium catalysts was studied, and the effects of different catalyst supports on the soot oxidation rate and CO2 selectivity were investigated. The results showed that V/MCM-41 and V/mordenite achieved 100% soot oxidation after 54 minutes of reaction. The redox properties of the catalyst were found to be crucial for the soot oxidation process. The study also revealed that higher discharge power, higher gas flow rate, and lower reaction temperature were beneficial for soot oxidation rate, but had a negative effect on CO2 selectivity. The proposed plasma-catalysis method showed unique advantages and could potentially be applied for the regeneration of diesel particulate filters (DPF) at low temperatures.