期刊
CHEMISTRYOPEN
卷 11, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.202200065
关键词
aqueous binders; lithium nickel manganese oxide; lithium titanate; Li-ion
资金
- Haldor Topsoe A/S, Denmark
- Swedish Energy Agency [45518-1]
- STand UP for Energy
- EU
- European Union [875126]
This study compares the effects of two water-soluble binders (CMC and SA) with N-methylpyrrolidone-soluble PVdF-HFP on the electrochemical performance of high-voltage LNMO cathodes. The results show that the cathodes prepared with water-soluble binders exhibit similar performance to PVdF-HFP at room temperature, but have higher cycling stability at 55 degrees C.
Two water-soluble binders of carboxymethyl cellulose (CMC) and sodium alginate (SA) have been studied in comparison with N-methylpyrrolidone-soluble poly(vinylidene difluoride-co-hexafluoropropylene) (PVdF-HFP) to understand their effect on the electrochemical performance of a high-voltage lithium nickel manganese oxide (LNMO) cathode. The electrochemical performance has been investigated in full cells using a Li4Ti5O12 (LTO) anode. At room temperature, LNMO cathodes prepared with aqueous binders provided a similar electrochemical performance as those prepared with PVdF-HFP. However, at 55 degrees C, the full cells containing LNMO with the aqueous binders showed higher cycling stability. The results are supported by intermittent current interruption resistance measurements, wherein the electrodes with SA showed lower resistance. The surface layer formed on the electrodes after cycling has been characterized by X-ray photoelectron spectroscopy. The amount of transition metal dissolutions was comparable for all three cells. However, the amount of hydrogen fluoride (HF) content in the electrolyte cycled at 55 degrees C is lower in the cell with the SA binder. These results suggest that use of water-soluble binders could provide a practical and more sustainable alternative to PVdF-based binders for the fabrication of LNMO electrodes.
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