☆ 4.5 Review

Recent Advancements in Metal-catalysts Design for CO2/Epoxide Reactions

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2022)

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Review Chemistry, Physical

Recent developments in state-of-the-art silica-modified catalysts for the fixation of CO2 in epoxides to form organic carbonates

Navya Anna Raju et al.

Summary: This review presents recent progress in the synthesis of cyclic carbonates through the cycloaddition reaction of CO2 with epoxides using silica-modified catalysts. Different classes of silica-based catalysts, including DFNS, MCM-41, SBA-15, and various ionic liquid-functionalized, metal-containing, and miscellaneous silica-based catalysts, are reviewed and discussed. The high surface area and diverse properties of silica-modified catalysts enable co-operative catalysis, resulting in superior conversion, selectivity, and yield compared to other homogeneous catalysts. The influence of reaction parameters and mechanistic details are given specific attention, and future opportunities for advanced silica-modified catalysts in CO2 conversion are highlighted.

SUSTAINABLE ENERGY & FUELS (2022)

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Article Chemistry, Multidisciplinary

Task-specific ionic liquids for carbon dioxide absorption and conversion into value-added products

Ye Qu et al.

Summary: This review summarizes the recent developments from 2019 to 2021 on task-specific ionic liquids (TSILs) with modulable properties for CO2 absorption and conversion. The introduction of specific functional groups, such as amino, amine, and ether groups, enhances the CO2 affinity, absorption capacity, and catalytic activity of TSILs. The construction of C-O bonds and C-N bonds is also highlighted for CO2 thermal catalytic conversion. The understanding gained from this review can provide perspectives for practical CO2 absorption and transformation by TSILs.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2022)

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Article Chemistry, Applied

Alternating copolymerization of CO2 and cyclohexene oxide initiated by rare-earth metal complexes stabilized by o-phenylenediamine-bridged tris(phenolate) ligand

Quanyou Yao et al.

Summary: A series of rare-earth metal complexes stabilized by tris(phenolate) ligands were synthesized and applied in the copolymerization of CO2 and cyclohexene oxide. The addition of benzyl alcohol improved the polymerization yields and selectivity. The reaction between benzyl alcohol and the rare-earth metal complexes resulted in the formation of dinuclear complexes.

JOURNAL OF RARE EARTHS (2022)

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Article Chemistry, Multidisciplinary

[OSSO]-Type Chromium(III) Complexes for the Reaction of CO2 with Epoxides

Fatemeh Niknam et al.

Summary: In this study, four new mononuclear Cr(III) complexes bearing [OSSO]-type bis-thioether-diphenolate ligands were synthesized and characterized. These complexes, in combination with PPNCl, were found to promote the coupling of CO2 with epoxides, leading to the selective formation of either polycarbonate or cyclic carbonate depending on the substrate and reaction conditions.

CHEMPLUSCHEM (2022)

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Article Engineering, Chemical

The importance of the bite angle of metal(III) salen catalysts in the sequestration of CO2 with epoxides in mild conditions

Anna Vidal-Lopez et al.

Summary: CO2 sequestration by reaction with epoxides is a key tool to solve the problem of CO2 emissions in the environment. This study focuses on the formation of cyclic organic carbonates catalyzed by metal-salen complexes and compares the performance of different metals. Density functional theory calculations analyze the structure and electronics of the catalysts to assess their efficiency and reaction conditions.

GREEN CHEMICAL ENGINEERING (2022)

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Review Chemistry, Multidisciplinary

Synthesis of porous poly(ionic liquid)s for chemical CO2 fixation with epoxides

Guoqing Li et al.

Summary: This review summarizes the recent progress in the synthesis and post-synthesis of porous poly(ionic liquid)s (PILs) catalysts for carbon dioxide (CO2) cycloaddition. The synthesis methods and catalytic behaviors of porous PILs in CO2 cycloaddition are discussed. It is highlighted that the rational design of IL monomers and optimization of synthetic parameters are crucial for developing high-performance catalysts.

GREEN CHEMISTRY (2022)

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Review Chemistry, Physical

Homogeneous and Heterogeneous Ionic Liquid System: Promising Ideal Catalysts for the Fixation of CO2 into Cyclic Carbonates

Zhuo-Jian Li et al.

Summary: This article reviews recent literature on the use of ionic liquid catalysts to fix carbon dioxide into cyclic carbonates, discusses the progress of current research and the problems that need to be addressed, and summarizes the basic principles for designing ionic liquid catalysts for the reaction in question as well as highlighting directions for future research.

CHEMCATCHEM (2021)

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Article Chemistry, Inorganic & Nuclear

Toward a Neutral Single-Component Amidinate Iodide Aluminum Catalyst for the CO2 Fixation into Cyclic Carbonates

Sebastian Saltarini et al.

Summary: This study involved the synthesis of a new iodide aluminum complex and its catalytic activity in the formation of cyclic carbonates, providing insights for the design of more active halide catalysts in the future.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Organic

Chiral titanium(IV) and vanadium(V) salen complexes as catalysts for carbon dioxide and epoxide coupling reactions

Svetlana A. Kuznetsova et al.

Summary: Chiral titanium(IV) and vanadium(V) salen complexes catalyse the synthesis of cyclic carbonates from carbon dioxide and epoxides under mild conditions, yielding racemic products. The mechanism proposed involves Lewis base catalysis for carbon dioxide activation instead of the commonly proposed Lewis acid catalysed activation of the epoxide.

TETRAHEDRON (2021)

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Review Chemistry, Multidisciplinary

Aliphatic Polycarbonates from Cyclic Carbonate Monomers and Their Application as Biomaterials

Wei Yu et al.

Summary: Aliphatic polycarbonates are gaining attention as biomaterials due to their biocompatibility and tunable degradation, with the ability to introduce functional handles through careful design of cyclic carbonate monomers. These materials have been widely explored for a variety of biomedical applications, from drug delivery to tissue regeneration and vascular graft design, showing great potential for therapeutic use in vitro and in vivo.

CHEMICAL REVIEWS (2021)

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Review Chemistry, Inorganic & Nuclear

[OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis

Veronica Paradiso et al.

Summary: Since the report in 2003, metal complexes with [OSSO]-bisphenolate ligands have been successfully used in various branches of homogeneous catalysis, creating a new research field. This review focuses on polymerization reactions catalyzed by these complexes, covering traditional monomers like fossil-derived olefins as well as newer and greener applications such as terpene polymerization and CO2 utilization.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Inorganic & Nuclear

Highly Active Chromium Complexes Supported by Constrained Schiff-Base Ligands for Cycloaddition of Carbon Dioxide to Epoxides

Jiraya Kiriratnikom et al.

Summary: Constrained Schiff-base ligands based on the well-known salen ligands were developed, leading to the synthesis of chromium complexes that acted as catalysts for the conversion of epoxides and CO2 into cyclic carbonates. Certain catalysts exhibited very high catalytic activity, with a turnover frequency of up to 14800 h(-1), showing 100% selectivity for the formation of terminal cyclic carbonates from various epoxide substrates.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Metal complexes bearing ONO ligands as highly active catalysts in carbon dioxide and epoxide coupling reactions

Bianca K. Munoz et al.

Summary: The paper discusses the use of metal complexes as catalysts in the synthesis of propylene carbonate from carbon dioxide and propylene oxide. Iron and manganese complexes showed significantly higher activities compared to new cobalt complexes. By optimizing the conditions, a TOF of 1600 h-1 was achieved with the manganese (II) complex 2.

INORGANICA CHIMICA ACTA (2021)

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Article Chemistry, Physical

Mechanism and Design Principles for Controlling Stereoselectivity in the Copolymerization of CO2/Cyclohexene Oxide by Indium(III) Phosphasalen Catalysts

Yernaidu Reddi et al.

Summary: The study characterizes the initiation and propagation steps of indium(III) phosphasalen catalysts through theoretical analysis, revealing unique mechanisms for their reactions with CO2 and CHO. The interaction of phosphasalen ligands with CHO and carbonate-terminated growing chains leads to high levels of isotacticity in the resulting polymer.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

Heterotrinuclear Ring Opening Copolymerization Catalysis: Structure-activity Relationships

Alex J. Plajer et al.

Summary: Heteronuclear complexes exhibit high catalytic activity in ring opening copolymerizations. By studying a series of trinuclear complexes, it was found that certain catalysts show high activity for specific reactions, such as CHO/CO2 ROCOP and CHO/ PA copolymerization, allowing for controlled polyether block formation. These findings can guide future catalyst design and inspire other CO2 utilization processes.

ACS CATALYSIS (2021)

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Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity

Alex J. Plajer et al.

Summary: A new catalyst class demonstrates exceptional selectivity and the ability to switch between different polymerization cycles, allowing for precise control of CO2 placement in polymers and access to new polymer chemistries. The best catalyst is a trinuclear dizinc(II)sodium(I) complex with excellent reaction rates and no need for additives or co-catalysts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Tolerant Bimetallic Macrocyclic [OSSO]-Type Zinc Complexes for Efficient CO2 Fixation into Cyclic Carbonates

Junwu Chen et al.

Summary: A new type of sustainable bimetallic zinc complexes has been developed for the chemical fixation of carbon dioxide into cyclic carbonates. The catalyst showed excellent performance with high stability to moisture and oxygen, resistance to impurities, and good recyclability. The catalytic mechanism involves a Lewis acidic zinc center and a nucleophilic halide counterion from the cocatalyst.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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A review for Metal-Organic Frameworks (MOFs) utilization in capture and conversion of carbon dioxide into valuable products

Fayez Nasir Al-Rowaili et al.

Summary: MOFs materials have shown great potential in capturing and converting CO2 due to their unique chemical properties and high internal surface area. By studying the application of MOFs as catalysts, it is expected to enhance ecosystem stability and promote sustainable development in the energy sector.

JOURNAL OF CO2 UTILIZATION (2021)

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Review Chemistry, Multidisciplinary

Direct synthesis of cyclic carbonates from olefins and CO2: Single- or multi-component catalytic systems via epoxide or halohydrin intermediate

Feng Han et al.

Summary: The conversion of CO2 to high value-added chemicals is urgent due to the rise in carbon dioxide emissions and its importance as a renewable chlorine source. Developing efficient catalytic systems for the synthesis of cyclic carbonates is crucial for practical applications. The review article discusses the comprehensive developments in catalytic systems, classified into transition metal and transition-metal-free ones, with a focus on single- or multi-component catalytic systems. Transition-metal-free systems mainly involve quaternary ammonium salts or ionic liquids, while multi-component catalytic systems contain noble and nonnoble metals along with quaternary ammonium salts for catalysis. Insights from the intermediates in the mechanisms are presented for designing multifunctional catalysts and developing new transformation strategies.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Applied

Photocatalytic Synthesis of Substituted Cyclic Carbonate Monomers for Ring-Opening Polymerization

Cristina Maquilon et al.

Summary: An operationally mild, ruthenium-based photocatalytic protocol has been developed for the conversion of gamma-mono- and gamma,gamma-disubstituted allyl carbonates to substituted six-membered cyclic carbonates. The variation and diversification of carbonate ring substitution provides access to new monomers useful in ring-opening polymerization, leading to polycarbonates with potentially tailored properties.

ADVANCED SYNTHESIS & CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Heterodinuclear Zn(II), Mg(II) or Co(III) with Na(I) Catalysts for Carbon Dioxide and Cyclohexene Oxide Ring Opening Copolymerizations

Wouter Lindeboom et al.

Summary: A series of heterodinuclear catalysts show good performance in the ring opening copolymerization of cyclohexene oxide and carbon dioxide, indicating the importance of auxiliary ligands and metal combinations in the design of efficient catalysts for carbon dioxide copolymerizations.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Inorganic & Nuclear

Metal-Cocatalyst Interaction Governs the Catalytic Activity of MII-Porphyrazines for Chemical Fixation of CO2

Julia P. S. C. Leal et al.

Summary: A series of porphyrazines were synthesized and tested as catalysts for the cycloaddition of CO2 to epoxides, with M(II)Pz bearing trifluoromethyl groups showing the best conversion. The type and concentration of cocatalyst had a notable effect on reaction yields, and the interaction between metal and cocatalyst may govern the reaction rate, as suggested by experimental results.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Synthesis, Characterization, and Catalytic Study of Amine-Bridged Bis(phenolato) Co(II) and Co(II/III)-M(I) Complexes (M = K or Na)

Xinyi He et al.

Summary: Co(II) complexes 1-3 were synthesized through reactions of bis(phenols) with CoCl2 or Co(OAc)(2), which were oxidized to generate mixed valence Co(II/III) complexes 4 and 5. The presence of alkali compounds led to the formation of Co-alkali metal heterometallic complexes, with complexes 1-5 showing good activity in the cyclo-addition of epoxides and CO2. Co(II/III)-Na(I) complex 5 demonstrated enhanced activity with bulkier substrates, but limited activity in the copolymerization of epoxide and CO2.

INORGANIC CHEMISTRY (2021)

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Editorial Material Chemistry, Multidisciplinary

Can CO2 and Renewable Carbon Be Primary Resources for Sustainable Fuels and Chemicals?

M. M. Faruque Hasan et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

Sustainable synthesis of five-membered heterocycles using carbon dioxide and Fe-iminopyridine catalysts

Jae Hyung Kim et al.

Summary: Sustainable Fe-iminopyridine catalysts were investigated for the formation of heterocycles and valued chemicals from carbon dioxide and specific substrates. The catalysts, prepared by self-assembly, contain a hydrogen bond donor and a nucleophilic imidazole group for activating the substrates and CO2 electrophile, respectively. This approach provides a green method for CO2 recycling and production of chemicals with potential industrial applications.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Multidisciplinary

Unexpected ferrate species as single-component catalyst for the cycloaddition of CO2 to epoxides

Nicola Panza et al.

Summary: A soluble ferrate salt was synthesized and found to exhibit good activity and selectivity in CO2 cycloaddition reactions with epoxides. The system can produce cyclic organic carbonates without the need for a co-catalyst under solvent-free conditions.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Physical

Theoretical investigation on conversion of CO2 with epoxides to cyclic carbonates by bifunctional metal-salen complexes bearing ionic liquid substsituents

Hui-Qing Yang et al.

Summary: A series of bifunctional metal-salen complexes bearing ionic liquid substituents were investigated as catalysts for the synthesis of cyclic carbonates from carbon dioxide and epoxides using DFT and energy span model. The results indicate that the three-step mechanism is more favorable than the two-step mechanism, and the interaction between the oxygen atom of epoxides and the central metal plays a key role in determining the catalytic activity of the metal-salen complexes.

MOLECULAR CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Cyclic organic carbonates from furanics: Opportunities and challenges

Nicola Bragato et al.

Summary: Furanic compounds, such as furfural and 5-hydroxymethylfurfural, are promising platform chemicals that can be derived from hemicellulose and cellulose in residual biomass. They can be transformed into cyclic organic carbonates suitable for various synthetic and material applications. The furan moiety can be further functionalized through Diels-Alder reactions, increasing the range of applications for resulting functional molecules and polymers while reducing toxicity.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Cyclic carbonates synthesised from CO2: Applications, challenges and recent research trends

Paolo P. Pescarmona

Summary: Cyclic carbonates can be prepared using carbon dioxide and have applications as green solvents and sustainable alternatives. Current research trends indicate their potential in the chemical industry.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2021)

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Review Chemistry, Physical

Synthesis of metalloporphyrin-based porous organic polymers and their functionalization for conversion of CO2 into cyclic carbonates: recent advances, opportunities and challenges

Rongchang Luo et al.

Summary: This review discusses the recent advances in the design and synthesis of metalloporphyrin-based POPs for CO2 catalysis, focusing on the conversion of CO2 into cyclic carbonates and the diverse synthetic strategies for preparing these materials with different functionalities and compositions. The exploration of single/multi-active-site synergistic catalytic models provides theoretical guidance for multifunctionalization of metalloporphyrin-based POPs, while also highlighting key opportunities and challenges in the field for future research and industrial applications.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Inorganic & Nuclear

An octahedral cobalt(iii) complex based on cheap 1,2-phenylenediamine as a bifunctional metal-templated hydrogen bond donor catalyst for fixation of CO2 with epoxides under ambient conditions

Mikhail A. Emelyanov et al.

Summary: A next-generation octahedral Co(III) complex was designed based on cheap commercially available materials, which efficiently catalyzed the reaction of epoxides with carbon dioxide to produce valuable cyclic carbonates under ambient conditions. The catalyst showed high catalytic activity and selectivity, achieving TON and TOF values of 38 and 1.6, respectively, at a low catalyst loading under solvent- and co-catalyst-free conditions.

INORGANIC CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Multidisciplinary

Cycloaddition of carbon dioxide and epoxides catalyzed by rare earth metal complexes bearing a Trost ligand

Jun Cheng et al.

Summary: A series of rare earth metal complexes based on Trost ligands were synthesized and successfully catalyzed the cycloaddition of carbon dioxide and epoxides. The optimal catalyst system was found to be 1 mol% Sm-based complex 1 with 2 mol% TBAB, forming monosubstituted cyclic carbonate at 70 degrees C. For the more challenging disubstituted epoxides, cyclic carbonates were obtained at elevated CO2 pressure of 0.7 MPa.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Physical

Dinuclear [OSSO]-Fe complexes for the reaction of CO2 with epoxides

Veronica Paradiso et al.

Summary: A dinuclear iron-based catalytic system with a new alkyl-bridged bis-[OSSO]-type ligand was reported for the coupling of CO2 with epoxides, achieving a turnover frequency of up to 1680 h(-1) for propylene carbonate formation. A bimetallic cooperative reaction mechanism was proposed based on kinetic analyses, providing insights for the development of more efficient catalysts.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

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Article Chemistry, Physical

Spiers Memorial Lecture: CO2 utilization: why, why now, and how?

Volker Sick

Summary: This article discusses the necessity, opportunities, boundary conditions, potential pitfalls, and key requirements for advancing technologies related to carbon dioxide utilization. It points out that CDU is gaining rapid traction as a mainstream climate-relevant solution.

FARADAY DISCUSSIONS (2021)

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Review Chemistry, Multidisciplinary

Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

Vatcharaporn Aomchad et al.

Summary: Biomass-related feedstock can be used as a coupling partner with CO2, allowing the development of more functional and complex carbonate architectures. This development has become an important part of new and more sustainable material designs in recent years.

GREEN CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Recent developments in organocatalysed transformations of epoxides and carbon dioxide into cyclic carbonates

Liping Guo et al.

Summary: This review focuses on the rapidly evolving field of organocatalysed cyclic carbonate synthesis, covering mechanisms, catalyst systems, key parameters, and future challenges. The importance of green metrics and catalyst requirements are highlighted throughout the article.

GREEN CHEMISTRY (2021)

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Update and Challenges in Carbon Dioxide-Based Polycarbonate Synthesis

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CHEMSUSCHEM (2020)

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A Novel [OSSO]-Type Chromium(III) Complex as a Versatile Catalyst for Copolymerization of Carbon Dioxide with Epoxides

Francesco Della Monica et al.

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Group 4 complexes as catalysts for the transformation of CO2 into polycarbonates and cyclic carbonates

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Ti(IV)-Tris(phenolate) Catalyst Systems for the Ring-Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide

Sumesh K. Raman et al.

ORGANOMETALLICS (2020)

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Mechanistic Insights into Cycloaddition of CO2 with Epoxide Catalyzed by a Bimetallic (Salen)Fe(II)Cl2 Complex with/without a Cocatalyst

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Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides

Arron C. Deacy et al.

NATURE CHEMISTRY (2020)

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Unlocking the Potential of Substrate-Directed CO2Activation and Conversion: Pushing the Boundaries of Catalytic Cyclic Carbonate and Carbamate Formation

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CHEMSUSCHEM (2020)

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Co(III)/Alkali-Metal(I) Heterodinuclear Catalysts for the Ring-Opening Copolymerization of CO2 and Propylene Oxide

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Rare-Earth Metal Complexes Supported by Polydentate Phenoxy- Type Ligand Platforms: C-H Activation Reactivity and CO2/Epoxide Copolymerization Catalysis

Liye Qu et al.

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Catalysis of carbon dioxide and oxetanes to produce aliphatic polycarbonates

Gulzar A. Bhat et al.

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Francesco Della Monica et al.

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Aluminum porphyrins with quaternary ammonium halides as catalysts for copolymerization of cyclohexene oxide and CO2: metal-ligand cooperative catalysis

Jingyuan Deng et al.

CHEMICAL SCIENCE (2020)

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The technological and economic prospects for CO2 utilization and removal

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Homogeneous Iron Catalysts in the Reaction of Epoxides with Carbon Dioxide

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Multifunctional and Sustainable Fe-Iminopyridine Complexes for the Synthesis of Cyclic Carbonates

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CHEMSUSCHEM (2019)

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Polynuclear alkoxy-zinc complexes of bowl-shaped macrocycles and their use in the copolymerisation of cyclohexene oxide and CO2

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Catalytic Strategies for the Cycloaddition of Pure, Diluted, and Waste CO2 to Epoxides under Ambient Conditions

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Indium Catalysts for Low-Pressure CO2/Epoxide Ring-Opening Copolymerization: Evidence for a Mononuclear Mechanism?

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[OSSO]-Type Iron(III) Complexes for the Low-Pressure Reaction of Carbon Dioxide with Epoxides: Catalytic Activity, Reaction Kinetics, and Computational Study

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Groups 1, 2 and Zn(II) Heterodinuclear Catalysts for Epoxide/CO2 Ring-Opening Copolymerization

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A quest for polycarbonates provided via sustainable epoxide/CO2 copolymerization processes

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Efficient Magnesium Catalysts for the Copolymerization of Epoxides and CO2; Using Water to Synthesize Polycarbonate Polyols

Michael R. Kember et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Article Polymer Science

ALTERNATING COPOLYMERIZATION OF CYCLOHEXENE OXIDE AND CARBON DIOXIDE UNDER COBALT PORPHYRIN CATALYST

Yu-sheng Qin et al.

CHINESE JOURNAL OF POLYMER SCIENCE (2011)

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Article Chemistry, Multidisciplinary

Mechanistic Investigation and Reaction Kinetics of the Low-Pressure Copolymerization of Cyclohexene Oxide and Carbon Dioxide Catalyzed by a Dizinc Complex

Fabian Jutz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Review Chemistry, Multidisciplinary

Salen-Complex-Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides

Antonello Decortes et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Review Chemistry, Multidisciplinary

Organic Carbonates as Solvents in Synthesis and Catalysis

Benjamin Schaeffner et al.

CHEMICAL REVIEWS (2010)

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Review Chemistry, Physical

The direct transformation of carbon dioxide to organic carbonates over heterogeneous catalysts

Wei-Li Dai et al.

APPLIED CATALYSIS A-GENERAL (2009)

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Article Chemistry, Inorganic & Nuclear

Di- and Tri-Zinc Catalysts for the Low-Pressure Copolymerization of CO2 and Cyclohexene Oxide

Michael R. Kember et al.

INORGANIC CHEMISTRY (2009)

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Review Chemistry, Multidisciplinary

Nonaqueous liquid electrolytes for lithium-based rechargeable batteries

K Xu

CHEMICAL REVIEWS (2004)

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Article Chemistry, Multidisciplinary

Comparative kinetic studies of the copolymerization of cyclohexene oxide and propylene oxide with carbon dioxide in the presence of chromium salen derivatives. In situ FTIR measurements of copolymer vs cyclic carbonate production

DJ Darensbourg et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

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Article Chemistry, Inorganic & Nuclear

The ethylsulfinate ligand:: A highly efficient initiating group for the zinc β-diiminate catalyzed copolymerization reaction of CO2 and epoxides

R Eberhardt et al.

ORGANOMETALLICS (2003)

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Review Chemistry, Multidisciplinary

Single-site β-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides:: Catalyst synthesis and unprecedented polymerization activity

M Cheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

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Article Chemistry, Multidisciplinary

Bis 2,6-difluorophenoxide dimeric complexes of zinc and cadmium and their phosphine adducts:: Lessons learned relative to carbon dioxide/cyclohexene oxide alternating copolymerization processes catalyzed by zinc phenoxides

DJ Darensbourg et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

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Article Chemistry, Multidisciplinary

Enantiomerically-enriched organic reagents via polymer synthesis: enantioselective copolymerization of cycloalkene oxides and CO2 using homogeneous, zinc-based catalysts

M Cheng et al.

CHEMICAL COMMUNICATIONS (2000)

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