期刊
ASIAN JOURNAL OF ORGANIC CHEMISTRY
卷 11, 期 9, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202200263
关键词
hydrogenation; solvent-free; heterogeneous catalyst; selective synthesis; 2; 2; 4; 4-tetramethylcyclobutane-1; 3-diol
In this study, a solvent-free ruthenium-on-carbon-catalyzed hydrogenation reaction of CBDK was developed for the production of cis-CBDO, and the reaction mechanism for cis-selectivity was proposed based on density functional theory (DFT) calculations.
In this study, ruthenium-on-carbon-catalyzed hydrogenation of CBDK was developed for the production of cis-CBDO under solvent-free conditions. Isomerization using a ruthenium catalyst and hydrogen gas may improve the selective formation of cis-CBDO. Moreover, the reaction mechanisms for cis-selectivity was proposed based on density functional theory (DFT) calculations.
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