4.6 Article

Superhigh-Luminance Ce:YAG Phosphor in Glass and Phosphor-in-Glass Film for Laser Lighting

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 10, 期 24, 页码 8105-8114

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c02657

关键词

laser lighting; Y3Al5O12; Ce3+; phosphor in glass; phosphor-in-glass film

资金

  1. Key Research and Development Project in Zhejiang Province [2021C01024]

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This study developed high-performance Ce:PiG with high quantum efficiency and luminous efficacy through a one-step co-sintering technology. Additionally, Ce:PiF fabricated on a sapphire substrate demonstrated enhanced laser saturation threshold and improved luminous efficacy. This work shows promising prospects for white laser lighting.
: Solid laser lighting with high photoelectric conversion efficiency and compact size has been increasingly vital in lighting applications. Extensive research has been conducted to obtain highquality color converters for application to high-power and highluminance laser lighting. Currently, Y3Al5O12:Ce3+ phosphor in glass (Ce:PiG) and Y3Al5O12:Ce3+ phosphor-in-glass film (Ce:PiF) possessing high efficiency, low cost, easy fabrication, and controllable chromaticity are becoming the most mainstream research directions. In this study, by modifying the glass particle size and sintering temperature, investigating the relevant host glass, and so forth, highperformance Ce:PiG was developed through a one-step co-sintering technology. It possesses a high internal quantum efficiency, approaching 100% of the original phosphors (92.5%). The luminous efficacy (LE) of the Ce:PiG was 240 lm/W at 2.18 W/mm2 under 450 nm blue laser diode (LD) excitation, which is the best result yet reported. Furthermore, to enhance the laser saturation threshold, the fabricated Ce:PiF relying on a sapphire substrate can withstand an 8 W/mm2 blue incident power density. The obtained sample can even reach an LE of 251.5 lm/W, which is an obvious improvement to Ce:PiG. In addition, the result, an LD module combined with the sample that meets the standard white light source, indicates that this work has good prospects for white laser lighting.

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