Adsorption of Cationic Pollutants from Water by Cotton Rope Coated with Cyclodextrin Polymers

The contamination from perilous organic compounds (pesticide and dyes) in water generates a significant problem for the environment and humans. A modified textile was prepared by a coating of anionic cyclodextrin polymer, obtained from the cross-linking between citric acid and beta-cyclodextrin in the presence of poly (vinyl alcohol), on the cotton cord for cationic pollutant removal from an aqueous solution. Its physicochemical properties were also characterized by gravimetry, titration, stereomicroscopy, SEM, TGA, C-13 NMR, and ATR-FTIR. The CC2 system exhibited 79.2% coating yield, 1.12 mmol/g COOH groups, 91.3% paraquat (PQ) removal, 97.0% methylene blue (MB) removal, and 98.3% crystal violet (CV) removal for 25 mg/L of initial concentration. The kinetics was fitted to the pseudo-second-order model using 6 h of contact time. The isotherm was suitable for the Langmuir isotherm with a maximum adsorption of 26.9 mg/g (PQ), 23.7 mg/g (MB), and 30.3 mg/g (CV). After 120 h of contact time in water and 5% v/v of HCI in ethanol, the weight loss was 7.5% and 5.6%, respectively. Finally, the recyclability performance reached 84.8% (PQ), 95.2% (MB), and 96.9% (CV) after five reuses.

Automated summary

Contamination from hazardous organic compounds in water is a significant problem. In this study, a modified textile coated with anionic cyclodextrin polymer was used to remove cationic pollutants from aqueous solutions. The physicochemical properties of the modified textile were characterized, and it showed a high removal efficiency for paraquat, methylene blue, and crystal violet. The kinetics and isotherm of the adsorption process were also studied. The modified textile exhibited good recyclability performance.