期刊
POLYMERS
卷 14, 期 14, 页码 -出版社
MDPI
DOI: 10.3390/polym14142802
关键词
poly (lactic acid); grafted starch nanocrystals (g-SNCs); crystallization; crystal structures; microstructure; permeability relations
资金
- Fonds de Recherche du Quebec Nature et Technologie (FRQNT)
The study shows that the addition of grafted starch nanocrystals has a significant impact on the oxygen and water vapor permeability of poly(lactic acid), leading to a reduction in permeability by approximately 70% and 50% respectively. This has the potential to develop PLA nanocomposites for use in food packaging applications.
The present work seeks to determine the impact of weight percentage (wt%) of grafted starch nanocrystals (g-SNCs) on the oxygen and water vapour permeability of poly (lactic acid), PLA. Changes in the oxygen and water vapour permeability of PLA due to changes in PLA's crystalline structures and lamellar thickness were quantified. To this end, 3, 5, and 7 wt% of g-SNC nanoparticles were blended with PLA using the solvent casting method in order to study impact of g-SNC nanoparticles on crystallization behaviour, long spacing period, melting behavior, and oxygen and water barrier properties of PLA nanocomposites. This was achieved by wide-angle X-ray diffraction (WAXD), small-angle X-ray diffraction (SAXD), differential scanning calorimetry (DSC), and oxygen and water vapour permeability machine. The results of the WAXD and SAXD analysis show that the addition of 5 wt% g-SNC in PLA induces alpha crystal structure at a lower crystallization time, while it significantly increases the alpha crystal thickness of PLA, in comparison to neat PLA. However, when g-SNC concentrations were altered (i.e., 3 or 7 wt%), the crystallization time was found to increase due to the thermodynamic barrier of crystallization. Finally, the oxygen and water vapour permeability of PLA/SNC-g-LA (5 wt%) nanocomposite film were found to be reduced by similar to 70% and similar to 50%, respectively, when compared to the neat PLA film. This can lead to the development of PLA nanocomposites with high potential for applications in food packaging.
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