期刊
POLYMERS
卷 14, 期 12, 页码 -出版社
MDPI
DOI: 10.3390/polym14122433
关键词
bioinspired; ion-crosslinked; hierarchical structure; mechanical properties; alginate
资金
- Fundamental Research Funds for the Central Universities [2020JBM071]
- National Natural Science Foundation of China [62075005, 52172081]
In this study, nacre-inspired montmorillonite-alginate hybrid films with excellent mechanical properties were fabricated, and the effects of ionic crosslinking strength and hydrogen bond interaction on the mechanical properties were studied.
The natural nacre has a regular ordered layered structure of calcium carbonate tablets and ion crosslinking proteins stacked alternately, showing outstanding mechanical properties. Inspired by nacre, we fabricated different divalent metal cation-crosslinked montmorillonite-alginate hybrid films (MMT-ALG-X2+; X2+ = Cu2+, Cd2+, Ba2+, Ca2+, Ni2+, Co2+ or Mn2+). The effect of ionic crosslinking strength and hydrogen bond interaction on the mechanical properties of the nacre-mimetics was studied. With the cations affinities with ALG being increased (Mn2+ < Co2+ = Ni2+ < Ca2+ < Ba2+ < Cd2+ < Cu2+), the tensile strength of nacre-mimetics showed two opposite influence trends: Weak ionic crosslinking (Mn2+, Co2+, Ni2+ and Ca2+) can synergize with hydrogen bonds to greatly increase the tensile properties of the sample; Strong ionic crosslinking (Ba2+, Cd2+, Cu2+) and hydrogen bonding form a competitive relationship, resulting in a rapid decrease in mechanical properties. Mn2+ crosslinking generates optimal strength of 288.0 +/- 15.2 MPa with an ultimate strain of 5.35 +/- 0.6%, obviously superior to natural nacre (135 MPa and 2%). These excellent mechanical properties arise from the optimum synergy of ion crosslinking and interfacial hydrogen bonds between crosslinked ALG and MMT nanosheets. In addition, these metal ion-crosslinked composite films show different colors, high visible transparency, and excellent UV shielding properties.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据