期刊
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
卷 206, 期 -, 页码 12-17出版社
ELSEVIER
DOI: 10.1016/j.elspec.2015.11.001
关键词
Titanium dichalcogenides; Resonant photoemission; Absorbtion spectroscopy; Multiplet calculation; Octahedrall coordination
类别
资金
- Russian-German Laboratory at BESSY bilateral Program [N 14201529-ST-1.1-P]
- FASO of Russia [01201463326]
- RFBR [14-03-00274_a, 13-03-96032_a]
- Multipurpose program of the Ural Division of RAS [15-9-2-30, 15-8-2-6]
- Ministry of Education and Science of Russia
- [20140467]
Influence of the covalence, octahedral distortion and the translation symmetry of the chromium ions in octahedral coordination on the electronic structure for compounds under investigation was clarified. Cr L-2,L-3 and Ti L-2,L-3 X-ray absorption spectra (XAS) along with atomic multiplet calculations and resonant Ti 2p-3d and Cr 2p-3d photoelectron spectra of valence band (RXPS) in the intercalated titanium dichalcogenides CrxTiX2 (X = Se, Te) and in the substitution compound TixCr1-xSe2 show the charge transfer between chromium and titanium sublattices. (C) 2015 Elsevier B.V. All rights reserved.
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