Advanced Photocatalytic Treatment of Wastewater Using Immobilized Titanium Dioxide as a Photocatalyst in a Pilot-Scale Reactor: Process Intensification

In many nations, particularly those experiencing water scarcity, novel approaches are being applied to clean wastewater. Heterogeneous photocatalysis is the most widely used of these approaches because it entails the decomposition of organic molecules into water and carbon dioxide, which is a more ecologically benign process. In our study, we studied the photocatalytic degradation process on the effluent flumequine. This treatment is made through a solar pilot reactor in the presence of immobilized titanium dioxide with three light intensities and two types of water as solvents. A variety of factors that might influence the rate of deterioration, such as flow rate, light intensity, and initial concentration, have been investigated. The maximal degradation of flumequine was achieved at more than 90% after 2.5 h under optimal conditions (an initial concentration of 5 mg/L, three lamp light intensities, and a flow rate of 29 L/h). By combining the oxidized agent H2O2 with this process, the photocatalytic activity was improved further to 97% under the same conditions. The mineralization of this product has also been tested using total organic carbon (TOC) analysis. A high mineralization rate has been recorded at around 50% for a high initial concentration (20 mg/L) at a flow rate of 126 L/h. The results demonstrated the highly effective removal of flumequine and the efficacy of this photocatalytic system.

Automated summary

Novel approaches are being applied to clean wastewater, with heterogeneous photocatalysis being the most widely used method. This study focuses on the photocatalytic degradation process of flumequine. By using immobilized titanium dioxide, different light intensities, and solvents, the factors influencing the degradation rate were investigated. The results showed highly effective removal of flumequine under optimal conditions, and the photocatalytic activity was further improved by combining an oxidized agent.