期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 780, 期 -, 页码 276-281出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2016.09.046
关键词
Molecularly imprinted polymers; Electrochemical sensor; Ascorbic add; Cyclic voltammetry; Copolymerization
资金
- Key Scientific Research Project of Henan Province Higher Education of China [15A150058]
- National Natural Science Foundation of China [21303044, 21303043]
In this work, a novel approach for selective and sensitive detection of ascorbic acid (AA) was proposed combined molecularly imprinted polymers and electrochemical sensor. The molecularly imprinted sensor was prepared by cyclic voltammetry on pencil graphite electrode with pyrrole (Py) and o-phenylenediamine (o-PD) as functional monomers and AA as template molecule. The sensor was evaluated through scanning electron microscope (SEM) and square wave voltammetry (SWV). The factors affecting electrochemical response of sensor were investigated and optimized. Under the optimum conditions, the imprinted sensor exhibited good selectivity and stability. The linear range of the sensor was 1 x 10(-6) to 1 x 10(-3) mol/L, meanwhile, the detection limit was 2.63 x 10(-7) mol/L (S/N = 3). This molecularly imprinted sensor has been successfully used in AA determination in real tablet samples with good recovery. (C) 2016 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据