期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 779, 期 -, 页码 18-24出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2016.01.023
关键词
Nano-impacts; Agglomeration; Finite difference simulation; Near-wall hindered diffusion
资金
- European Research Council under the European Union [320403]
The effects of reversible agglomeration and near-wall hindered diffusion are investigated in the context of nano impact experiments. A significant reduction in the mass transport to the electrode is observed due to the formation of slow-moving agglomerates. It is further demonstrated that in the presence of a rapid agglomeration process, larger agglomerated species are virtually unobservable, since the monomer is the dominant flux carrier. This observation is consistent with previously reported experimental data. (C) 2016 Elsevier B.V. All rights reserved.
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