期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 778, 期 -, 页码 110-115出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2016.08.020
关键词
Cobalt hydroxide; Nanomaterial; Specific capacitance; Cycling stability; Supercapacitor
资金
- Science and Technology Development Project of Jilin Province [20140101160JC]
- Jilin Province Department of Education [0520385, 0520386]
Sheet-like Co(OH)(2) or Co(OH)(2)/Ni(OH)(2) nanomaterials has been synthesized on conducting carbon fiber paper (CFP) via a simple electrochemical deposition. The microstructural, chemical bonding and surface morphology of the nanomaterials were investigated by X-ray diffraction (XRD), X-ray photoelectron specttoscopy (XPS) and scanning electron microscopy (SEM). And the electrochemical properties of nanomaterials were investigated by cyclic voltammetry and galvanostatic charge-discharge. Compared to Co(OH)(2), Co(OH)(2)/Ni(OH)2 nanomaterials exhibits not only a higher specific capacitance (1498 Fg(-1) than Co(OH)(2) (709 Fg(-1)) at a current density 2 Ag-1) but also a higher cycling stability (92.4% specific capacitance remain over 20,000 charge discharge cycles than Co(OH)(2) (723% remains) at a high current density of 32 Ag-1). The introduction of Ni(OH)(2) brings a synergistic effect for the whole material. (C) 2016 Elsevier B.V. All rights reserved.
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