Approaching intrinsic dynamics of MXenes hybrid hydrogel for 3D printed multimodal intelligent devices with ultrahigh superelasticity and temperature sensitivity

Hydrogels are investigated broadly in flexible sensors which have been applied into wearable electronics. However, further application of hydrogels is restricted by the ambiguity of the sensing mechanisms, and the multi-functionalization of flexible sensing systems based on hydrogels in terms of cost, difficulty in integration, and device fabrication remains a challenge, obstructing the specific application scenarios. Herein, cost-effective, structure-specialized and scenario-applicable 3D printing of direct ink writing (DIW) technology fabricated two-dimensional (2D) transition metal carbides (MXenes) bonded hydrogel sensor with excellent strain and temperature sensing performance is developed. Gauge factor (GF) of 5.7 (0 - 191% strain) and high temperature sensitivity (-5.27% degrees C-1) within wide working range (0 - 80 degrees C) can be achieved. In particular, the corresponding mechanisms are clarified based on finite element analysis and the first use of in situ temperature-dependent Raman technology for hydrogels, and the printed sensor can realize precise temperature indication of shape memory solar array hinge. Cost effective device fabrication of powerful hydrogel sensors remains challenging. Here, the authors propose a cost-effective and structure-specialized direct ink writing technique for the fabrication of two-dimensional MXene bonded hydrogel sensors with excellent strain and temperature sensing performance.

Automated summary

Hydrogels are widely studied for flexible sensors in wearable electronics, but their further application is hindered by the ambiguity of sensing mechanisms and the challenges in multi-functionalization. In this study, a cost-effective direct ink writing technique is used to fabricate a 2D MXene bonded hydrogel sensor, which demonstrates excellent strain and temperature sensing performance. The sensing mechanisms are clarified using finite element analysis and in situ temperature-dependent Raman technology.