A 3D-Printed, Freestanding Carbon Lattice for Sodium Ion Batteries

Increasing mass loadings of battery electrodes critically enhances the energy density of an overall battery by eliminating much of the inactive components, while compacting the battery size and lowering the costs of the ingredients. A hard carbon microlattice, digitally designed and fabricated by stereolithography 3D-printing and pyrolysis, offers enormous potential for high-mass-loading electrodes. In this work, sodium-ion batteries using hard carbon microlattices produced by an inexpensive 3D printer are demonstrated. Controlled periodic carbon microlattices are created with enhanced ion transport through microchannels. Carbon microlattices with a beam width of 32.8 mu m reach a record-high areal capacity of 21.3 mAh cm(-2) at a loading of 98 mg cm(-2) without degrading performance, which is much higher than the conventional monolithic electrodes (approximate to 5.2 mAh cm(-2) at 92 mg cm(-2)). Furthermore, binder-free, pure-carbon elements of microlattices enable the tracking of structural changes in hard carbon that support the hypothesized intercalation of ions at plateau regions by temporal ex situ X-ray diffraction measurements. These results will advance the development of high-performance and low-cost anodes for sodium-ion batteries as well as help with understanding the mechanisms of ion intercalations in hard carbon, expanding the utilities of 3D-printed carbon architectures in both applications and fundamental studies.

Automated summary

This study demonstrates the use of inexpensive 3D printers to fabricate high-energy-density sodium-ion batteries with hard carbon microstructure electrodes. Periodic carbon microstructures with enhanced ion transport capabilities were created, achieving higher areal capacity compared to conventional monolithic electrodes. The use of binder-free pure-carbon microstructure elements allowed for tracking of structural changes and improved understanding of ion intercalation mechanisms in hard carbon.