Facile strategy to separate uranium (VI) using glued Amidoxime-functionalized composite beads synthesized from aqueous solution

Uranium is both an important resource and an environmental hazard. It is vital to separate/enrich uranium from liquid for energy production as well as for environmental protection. Herein, the amidoxime-functionalized mesoporous silica/calcium alginates (Al/MS-AO) were synthesized by co-condensation and post-gluing process. The morphology and the characteristics of the Al/MS-AO were studied by using Scanning electron microscope (SEM), energy dispersive spectrometer (EDS), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), N-2 adsorption-desorption and X-ray photoelectron spectroscopy (XPS). These analyses have also revealed the in-depth information of the materials including function groups, structure, and Uranium adsorption mechanism. Batch experiments were conducted, and the results suggest that the adsorption of uranium by Al/MS-AO is a spontaneous and endothermic process. This process can be described with the combination of a pseudo second order kinetic model and a Langmuir isotherm model. The maximum adsorption capacity achieved is 328.68 mg.g(-1). Three possible adsorption mechanisms are proposed, which involve the chemical chelation of the N and O atoms of amidoxime.

Automated summary

In this study, amidoxime-functionalized mesoporous silica/calcium alginates (Al/MS-AO) were synthesized and their morphology and characteristics were investigated. The results revealed the in-depth information of the materials including function groups, structure, and Uranium adsorption mechanism. The batch experiments showed that the adsorption of uranium by Al/MS-AO is a spontaneous and endothermic process, with a maximum adsorption capacity of 328.68 mg.g(-1).