Studying coalescence at different lengthscales: from films to droplets

The hydrodynamics of thin films is an important factor when it comes to the stability and rheology of multiphasic materials, such as foams, emulsions, and polymer blends. However, there have so far been only limited experimental studies addressing the dynamics of individual free-standing thin films at conditions similar to those encountered on macroscopic scales. In this article, we study a well-characterized system of a water-in-oil emulsion stabilized by a non-ionic surfactant (SPAN80) close to its CMC. We employ a dynamic thin film balance, to study the dynamics of freestanding films under both constant and time-varied pressure drops. We compare with the recently published results of Narayan et al. (2020) on colliding droplets of the same system with a hydrodynamic microfluidic trap, and show for the first time that agreement between the two lengthscales is possible, which indicates that the coalescence is indeed dominated by the dynamics in the film. We then address the scatter in the coalescence times and show that it can be affected by extrinsic factors, as well as by variations in the collision angle. Finally, we discuss the difficulties of extracting insight on the coalescence mechanism from coalescence time distributions when different effects such as impurities, small pressure variations, collision angle variations, and possible Marangoni-related instabilities are at play.

Automated summary

The dynamics of thin films in water-in-oil emulsions were studied using a dynamic thin film balance, showing that external factors and variations in collision angle can affect coalescence time distributions. Difficulty extracting insights on the coalescence mechanism from these distributions was also discussed.