☆ 4.7 Review

A critical review of the hydrogen production from biomass-based feedstocks: Challenge, solution, and future prospect

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2022)

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Article Engineering, Environmental

A high temperature tubular reactor with hybrid concentrated solar and electric heat supply for steam methane reforming

Jing Ma et al.

Summary: Solar-powered steam methane reforming is an efficient way to generate hydrogen and reduce carbon dioxide emissions. The high-temperature heat pipe reactor (HTPR) proposed in this study combines concentrated solar energy and photovoltaic electricity to achieve a round-the-clock reforming process. Experimental results showed high methane conversion and hydrogen purity, as well as stable operation for 24 hours, demonstrating the potential of HTPR in resolving unstable hydrogen production by renewable energy.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Physical

Effect of hydrogen on compression-ignition (CI) engine fueled with vegetable oil/biodiesel from various feedstocks: A review

S. Thiyagarajan et al.

Summary: Compression ignition (CI) engines using fossil diesel are major contributors to air pollution. Previous studies have attempted to replace fossil diesel with biofuels to reduce carbon dioxide emissions, but the performance has been sub-standard. Researchers have introduced hydrogen with biofuels in an attempt to improve engine performance. This study examines the effects of hydrogen addition with biodiesel/vegetable oil from various sources in CI engines.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

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Review Agricultural Engineering

Pilot-scale co-processing of lignocellulosic biomass, algae, shellfish waste via thermochemical approach: Recent progress and future directions

Peter Nai Yuh Yek et al.

Summary: Thermal co-processing of lignocellulosic and aquatic biomass has shown potential for producing high-value energy products, and scaling up to pilot-scale operations is crucial. Design and operation of pilot-scale reactors, as well as key parameters for biomass co-processing, are discussed. Techno-economic analysis reveals factors influencing sustainability, and different processing methods have varying advantages.

BIORESOURCE TECHNOLOGY (2022)

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Review Agricultural Engineering

Recent advances in biofuel production through metabolic engineering

Swati Joshi et al.

Summary: The rising global energy demands and climate crisis have created an unprecedented need for the bio-based circular economy. Metabolic engineering is at the forefront of developing microbial chassis for biofuel bio-foundries to meet the industrial needs for clean energy.

BIORESOURCE TECHNOLOGY (2022)

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Article Environmental Sciences

Progress in valorisation of agriculture, aquaculture and shellfish biomass into biochemicals and biomaterials towards sustainable bioeconomy

Wan Adibah Wan Mahari et al.

Summary: This article reviews the sustainable conversion of agricultural, aquaculture, and shellfish biomass and waste into alternative commodities, discussing recent progress and analysis of various valorisation technologies. These technologies have gained attention for producing bio-based chemicals and materials at viable prices, leading to reduced CO2 emissions and sustainable resource management.

CHEMOSPHERE (2022)

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Article Thermodynamics

Pyrolysis of biomass Tar model compound with various Ni-based catalysts: Influence of promoters characteristics on hydrogen-rich gas formation

Xueqin Li et al.

Summary: This paper studied the conditions and mechanism of hydrogen-rich gas produced from catalytic pyrolysis of toluene by various Ni-based catalysts. The results showed that Fe-modified Ni/HZSM-5 catalyst had the highest efficiency in hydrogen production. The smaller crystal particles, high surface area, and sufficient loading quality of Ni-Fe catalysts provided efficient active sites and promoted the pyrolysis process of toluene. The activity and stability of catalysts were also improved by Ce-modified Ni/ZSM-5 catalyst, but with lower hydrogen yield. Ni-Mg/HZSM-5 catalyst had the lowest activity and stability, attributed to nickel sintering and coke formation. The Ni-Fe/HZ5 catalyst maintained high catalytic activity even after two regenerations.

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Article Energy & Fuels

Hydrogen-rich syngas production from biomass pyrolysis and catalytic reforming using biochar-based catalysts

Yanjie Wang et al.

Summary: This study investigates the use of residual biochar-based catalyst in catalytic reforming process after biomass pyrolysis. The results show that biochar has abundant pore structure and catalytic activity, which is favorable for bio-oil reforming. The addition of Ni to biochar enables it to act as a support, reducing NiO to active Ni and protecting Ni from oxidation. It is found that 10wt% Ni/Char catalyst at 650 degrees C yields the optimal syngas production of 34.321 mmol per 1 g biomass. The addition of water significantly increases syngas production due to the thorough utilization of biological carbon.

FUEL (2022)

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Process simulation and optimization of groundnut shell biomass air gasification for hydrogen-enriched syngas production

Mehdi Faraji et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

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Article Engineering, Environmental

Syngas analysis by hybrid modeling of sewage sludge gasification in downdraft reactor: Validation and optimization

Karthickeyan Viswanathan et al.

Summary: This article addresses the thermochemical conversion of sewage sludge through a downdraft gasifier. It proposes a hybrid modeling approach using a two-zone equilibrium and one-zone kinetic model for sewage sludge gasification. The study finds that the syngas compositions and cold gas efficiency are sensitive to variations in gasifying agent flow rates, feedstock flow rate, and gasifier temperature and pressure. The article concludes by using an optimization algorithm to determine the optimal operating conditions under prescribed constraints.

WASTE MANAGEMENT (2022)

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Article Energy & Fuels

Split injection strategies based RCCI combustion analysis with waste cooking oil biofuel and methanol in an open ECU assisted CRDI engine

Nataraj Ganesan et al.

Summary: The present study investigates the combined effect of split injection techniques and RCCI-dual-fuel combustion in a single-cylinder CRDI research engine operated with waste cooking oil (WCO) bio-fuel and methanol. The experimental results show that this combination can significantly improve the thermal efficiency of the engine and reduce NOx and smoke emissions.

FUEL (2022)

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Article Energy & Fuels

Novel Petit grain bitter orange waste peel oil biofuel investigation in diesel engine with modified fuel injection pressure and bowl geometry

Karthickeyan Viswanathan et al.

Summary: This study investigates a novel biofuel feedstock, Petit grain bitter orange oil, and its potential as an alternative energy source. Through experimental testing and analysis, the fuel properties, chemical composition, and thermal analysis of this biofuel were determined. The results showed that it performs well in terms of emissions, but its performance and combustion characteristics are better with diesel fuel.

FUEL (2022)

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Article Chemistry, Applied

Highly stable Pt/CoAl2O4 catalysts in Aqueous-Phase Reforming of glycerol

A. J. Reynoso et al.

Summary: The addition of Pt to cobalt aluminate resulted in a synergistic effect that promoted the reduction of both Pt and Co species, as well as cobalt dispersion, increasing the amount of exposed metallic sites. Bimetallic catalysts showed excellent stability and activity in glycerol APR and WGS, but had lower selectivity to hydrogen.

CATALYSIS TODAY (2021)

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Article Engineering, Environmental

Catalytic conversions of CO2 to help mitigate climate change: Recent process developments

Maryam Takht Ravanchi et al.

Summary: Carbon dioxide, despite its negative reputation as a greenhouse gas and pollutant, can be utilized as a renewable, non-toxic, and cost-effective feedstock for chemical synthesis. The chemical conversion of CO2 not only reduces greenhouse gas emissions but also conserves fossil fuel resources. By integrating renewable energies, catalyst development, and separation technologies, a circular economy based on CO2 is feasible with advancements in catalysis and reaction engineering.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2021)

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Review Agricultural Engineering

Biomass-to-hydrogen: A review of main routes production, processes evaluation and techno-economical assessment

Thibaut Lepage et al.

Summary: This study reviews various approaches, including thermochemical, biological, and electrochemical, used for biomass-to-hydrogen conversion. It presents the advantages, limitations, and necessary improvements for each process. A techno-economic assessment highlights the promising potential of biomass-based hydrogen production but emphasizes the need for further advancements.

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Article Agricultural Engineering

Activated char supported Fe-Ni catalyst for syngas production from catalytic gasification of pine wood

Jianjun Hu et al.

Summary: In this study, Fe-Ni/AC catalyst was prepared and used for catalytic gasification of various biomass feedstocks. It was found that Fe-Ni/AC had an impact on the H2/CO ratio of syngas and exhibited different catalytic effects on different biomass feedstocks.

BIORESOURCE TECHNOLOGY (2021)

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Review Engineering, Chemical

Steam Reforming of Methanol for Hydrogen Production: A Critical Analysis of Catalysis, Processes, and Scope

Apoorva M. Ranjekar et al.

Summary: The hydrogen economy is actively developing, with methanol being a flexible alternative fuel of interest. Different metallic catalysts and their compositions play a crucial role in the steam reforming of methanol.

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Non-precious electrocatalysts for oxygen evolution reaction in anion exchange membrane water electrolysis: A mini review

Juchan Yang et al.

Summary: Anion exchange membrane water electrolysis is considered the next generation of green hydrogen production method that uses low-cost non-noble metal oxide electrocatalysts, but faces challenges of low activity and durability. Research focuses on improving the performance and stability of non-precious electrocatalysts.

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Assessment of product yields and catalyst deactivation in fixed and fluidized bed reactors in the steam reforming of biomass pyrolysis volatiles

Enara Fernandez et al.

Summary: The fixed bed reactor showed higher initial conversion and H-2 yield in the steam reforming of biomass fast pyrolysis volatiles, leading to lower catalyst deactivation compared to the fluidized bed reactor.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2021)

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Article Chemistry, Physical

Effect of catalyst distribution and structural properties of anode porous transport electrodes on the performance of anion exchange membrane water electrolysis

Ruixiang Wang et al.

Summary: Research shows that the distribution of catalyst in the anode porous transport electrodes affects the performance of anion exchange membrane (AEM) water electrolyzers, with denser catalyst layers promoting water diffusion to mitigate concentration overpotential. Decreasing the thickness of the anode porous transport electrodes enables good electrolysis performance with low catalyst loading.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Energy & Fuels

CO2 Utilization Technologies: A Techno-Economic Analysis for Synthetic Natural Gas Production

Szabolcs Szima et al.

Summary: This paper introduces an energy-efficient method for synthetic natural gas production using captured CO2 and renewable hydrogen, specifically comparing different renewable hydrogen sources and analyzing their economic viability. Among the options evaluated, photo-fermentation proved to be the most attractive in terms of cost, although biomass gasification becomes more viable when considering production capacities.

ENERGIES (2021)

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Review Thermodynamics

A comprehensive review of hydrogen production from methanol thermochemical conversion for sustainability

Gabriel Garcia et al.

Summary: This review discusses various methods of hydrogen production from methanol, with a focus on catalyst development and reactor technology. Copper-based catalysts are popular due to their high activity and selectivity but have stability issues, leading to exploration of other metals like zinc and chromium. Novel reactor structures such as porous copper fiber sintered-felt and membrane reactors have been explored for improved efficiency and energy savings.

ENERGY (2021)

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Article Energy & Fuels

Inherent CO2 Capture and H2 Production Enhancement in a New Glycerol Steam Reformer Coupled with Chemical Looping Combustion

Amirhossein Khazayialiabad et al.

Summary: The study introduces a new reactor configuration that integrates chemical looping combustion (CLC) system and glycerol steam reforming (GSR) process, compared with the conventional concept. By using the efficient oxygen carrier of NiO18-alpha Al2O3 particles, the proposed model shows a significant increase in hydrogen yield and glycerol conversion.

ENERGY & FUELS (2021)

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Article Energy & Fuels

Use of bio-glycerol for the production of synthesis gas by chemical looping reforming

Inaki Adanez-Rubio et al.

Summary: Chemical Looping Reforming (CLR) of glycerol has been demonstrated to produce high purity syngas without CO2 emissions. The main operating variables influence the composition and flow rates of the synthesis gas, with the oxygen-to-glycerol molar ratio being a key parameter.

FUEL (2021)

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Article Engineering, Chemical

Hydrogen production by methane steam reforming using metallic nickel hollow fiber membranes

Mingming Wang et al.

Summary: The study produced metallic nickel hollow fiber membranes with a dense skin layer and porous nickel substrate for hydrogen production from methane steam reforming. The membranes showed high efficiency and stability, making them a promising option for cost-effective hydrogen production at high temperatures.

JOURNAL OF MEMBRANE SCIENCE (2021)

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Article Engineering, Environmental

Recent progress in anti-coking Ni catalysts for thermo-catalytic conversion of greenhouse gases

Xingyuan Gao et al.

Summary: This review summarizes the latest developments of Ni-based catalysts for thermal-catalytic conversion of CO2 and CH4, covering various catalytic processes, modification strategies, reaction mechanisms, and the effects of reaction conditions on catalyst performance. Advanced techniques such as plasma and microwave integration are suggested to improve catalytic performance and energy efficiency.

PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2021)

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Article Chemistry, Physical

Partial Oxidation of Methane to Syngas via Formate Intermediate Found for a Ruthenium-Rhenium Bimetallic Catalyst

Lingcong Li et al.

Summary: The addition of Re to a Ru/Al2O3 catalyst changes the reaction mechanism, leading to increased production of CO for syngas, with Re playing a dual role in formate generation and steam reforming acceleration. Re is a main player in the catalytic reaction rather than a simple promoter.

ACS CATALYSIS (2021)

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Article Engineering, Environmental

Production of renewable fuels and chemicals from fats, oils, and grease (FOG) using homogeneous and heterogeneous catalysts: Design, validation, and optimization

Muhammad Ikhsan Taipabu et al.

Summary: Fats, oils, and grease (FOG) waste collected from kitchen and restaurant wastes can cause sewer blockage in many countries due to increased human activities. A new FOG waste-to-chemicals process has been developed to produce biodiesel and other by-products, demonstrating environmental benefits.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Thermodynamics

Carbon deposition in steam methane reforming over a Ni-based catalyst: Experimental and thermodynamic analysis

Dmitry Pashchenko et al.

Summary: The experimental investigation focused on steam methane reforming process over an industrial Ni-based catalyst to understand the impact of carbon deposition on methane conversion and pressure drop. Results showed that methane conversion rates varied with different operating conditions, with the most significant decrease observed at a steam-to-methane ratio of 0.5.

ENERGY (2021)

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Article Engineering, Environmental

Renewable hydrogen production from chemical looping steam reforming of biodiesel byproduct glycerol by mesoporous oxygen carriers

Binlin Dou et al.

Summary: The study investigated the use of Ni-based MCM41 and SBA-15 oxygen carriers in chemical looping steam reforming for hydrogen production, with and without CeO2 promoter. Analysis of synthesized oxygen carriers showed thermal decomposition reactions and the catalytic effects of the carriers were observed when CeO2 promoter was used.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Green & Sustainable Science & Technology

Water availability and water usage solutions for electrolysis in hydrogen production

Sofia G. Simoes et al.

Summary: Europe is committed to achieving a new growth strategy with no net greenhouse gas emissions by 2050, where hydrogen plays a key role. Portugal's strategy for H2 focuses on promoting an industry based on the hydrogen value chain. A new approach is presented in this work to assess the suitability of water sources for hydrogen production via water electrolysis, using a Sustainable Value Methodology. The evaluation of water sources in two different sites in Portugal reveals that public grid water is the most suitable source for electrolysis due to lower risk, costs and simplified permitting processes.

JOURNAL OF CLEANER PRODUCTION (2021)

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Article Engineering, Environmental

Greenhouse gas mitigation and hydrogen generation via enhanced ethylene glycol dry reforming on La-promoted Co/Al2O3 catalyst

Lau N. Jun et al.

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PROCESS SAFETY AND ENVIRONMENTAL PROTECTION (2021)

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Proceedings Paper Materials Science, Multidisciplinary

Extracted γ-Al2O3 from aluminum dross as a catalyst support for glycerol dry reforming reaction

Nurul Asmawati Roslan et al.

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MATERIALS TODAY-PROCEEDINGS (2021)

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Ammaru Ismaila et al.

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Derya Unlu et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Thermodynamic equilibrium analysis of steam methane reforming based on a conjugate solution of material balance and law action mass equations with the detailed energy balance

Dmitry Pashchenko

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2020)

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Intensified steam methane reforming coupled with Ca-Ni looping in a dual fluidized bed reactor system: A conceptual design

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Syngas upgrading in a membrane reactor with thin Pd-alloy supported membrane

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Activity of Ni-Cu-Al based catalyst for renewable hydrogen production from steam reforming of glycerol

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Assessment of CO2 capture options from various points in steam methane reforming for hydrogen production

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Perspective on hydrogen energy carrier and its automotive applications

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Hydrogen production by glycerol steam reforming with Pt/SiO2 and Ni/SiO2 catalysts

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Catalysts for methanol steam reforming-A review

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Hydrogen production from biomass tar by catalytic steam reforming

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2010)

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An economic survey of hydrogen production from conventional and alternative energy sources

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2010)

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Theoretical comparison of packed bed and fluidized bed membrane reactors for methane reforming

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A review of catalytic hydrogen production processes from biomass

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Design of a stable steam reforming catalyst-A promising route to sustainable hydrogen from biomass oxygenates

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Non-catalytic partial oxidation of bio-oil to synthesis gas for distributed hydrogen production

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Stability of bimetallic Pd-Zn catalysts for the steam reforming of methanol

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Hydrogen production from ethanol over Ir/CeO2 catalysts:: A comparative study of steam reforming, partial oxidation and oxidative steam reforming

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Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering

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Pyrolysis of wood/biomass for bio-oil: A critical review

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Electrolysis of water on (oxidized) metal surfaces

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CHEMICAL PHYSICS (2005)

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A review of catalytic issues and process conditions for renewable hydrogen and alkanes by aqueous-phase reforming of oxygenated hydrocarbons over supported metal catalysts

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APPLIED CATALYSIS B-ENVIRONMENTAL (2005)

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Comparison of conventional and membrane reactor fuel processors for hydrocarbon-based PEM fuel cell systems

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2004)

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Biohydrogen production: prospects and limitations to practical application

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2004)

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Recent developments in autothermal reforming and pre-reforming for synthesis gas production in GTL applications

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FUEL PROCESSING TECHNOLOGY (2003)

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Comprehensive comparison of efficiency and CO2 emissions between biomass energy conversion technologies - position of supercritical water gasification in biomass technologies

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Sustainable fermentative hydrogen production: challenges for process optimisation

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2002)

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Energy production from biomass (part 3): gasification technologies

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Steam reforming of methanol over a Cu/ZnO/Al2O3 catalyst:: a kinetic analysis and strategies for suppression of CO formation

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Conversion of hydrocarbons and alcohols for fuel cells

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JOURNAL OF POWER SOURCES (2002)

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Photo-electrochemical properties of the TiO2-Pt system in aqueous solutions

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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2002)

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Biomass resource facilities and biomass conversion processing for fuels and chemicals

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ENERGY CONVERSION AND MANAGEMENT (2001)

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Catalytic partial oxidation of natural gas at elevated pressure and low residence time

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