期刊
ORGANIC LETTERS
卷 24, 期 24, 页码 4433-4437出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c01657
关键词
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资金
- National Natural Science Foundation of China [22171197]
- Major Basic Research Project of the Natural Science Foundation of Jiangsu Higher Education Institutions [21KJA150002]
- National Local Joint Engineering Laboratory [SDGC2121]
- PAPD Project
- Open Research Fund of the School of Chemistry and Chemical Engineering, Henan Normal University
The Bi(OTf)(3)-promoted hydrosulfonylation of alkenes with sulfonyl hydrazides to produce branched sulfones is reported. Various branched sulfones were synthesized in moderate to good yields, highlighting the potential application of this reaction.
The Bi(OTf)(3)-promoted hydrosulfonylation of alkenes with sulfonyl hydrazides to produce branched sulfones is reported, in which various branched sulfones (>40 examples) have been prepared in moderate to good yields. The gram-scale reaction and synthesis of the experimental inhibitor precursor showed the potential application. A preliminary mechanistic study revealed that double-bond migration to form the alpha,beta-conjugated alkene is crucial for this transformation.
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