Stereoselective Cyclization Cascade of Dihydroquinoxalinones by Visible-Light Photocatalysis: Access to the Polycyclic Quinoxalin-2(1H)-ones

An intriguing stereoselective visible-light photo catalysis of dihydroquinoxalinone derivatives has been realized via cyclization with or without the solvolysis cascade. The reactions provided the polycyclic ring structures with efficient formation of multiple bonds and with high stereoselectivity. X-ray crystallography unequivocally determined the structures of five polycyclic products

Automated summary

The stereoselective visible-light photo catalysis of dihydroquinoxalinone derivatives via cyclization has efficiently formed polycyclic ring structures, with the formation of multiple bonds and high stereoselectivity.