4.8 Editorial Material

A handle on charge reorganization

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Article Chemistry, Multidisciplinary

Ion-pair reorganization regulates reactivity in photoredox catalysts

J. D. Earley et al.

Summary: Cyclometalated and polypyridyl complexes of d(6) metals have great potential as photoredox catalysts, and besides the known criteria for modifying activity, such as tuning redox potentials, absorption energy, excited-state lifetime, and quantum yield, ion pair reorganization may also be an important factor in controlling reactivity.

NATURE CHEMISTRY (2022)