Boosting sulfa redox kinetics by a pentacenetetrone redox mediator for high-energy-density lithium-sulfur batteries

Lithium-sulfur (Li-S) battery is considered as a promising energy storage system due to its ultrahigh theoretical energy density of 2,600 Wh.kg(-1). Redox mediation strategies have been proposed to promote the sluggish sulfur redox kinetics. Nevertheless, the applicability of redox mediators in practical high-energy-density Li-S batteries has seldomly been manifested. In this work, 5,7,12,14-pentacenetetrone (PT) is proposed as an effective redox mediator to promote the sulfur redox kinetics under practical working conditions. A high initial specific discharge capacity of 993 mAh.g(-1) is achieved at 0.1 C with high-sulfur-loading cathodes of 4.0 mg(s).cm(-2) and low electrolyte/sulfur (E/S) ratio of 5 mu L.mg s(-1). More importantly, practical Li-S pouch cells with the PT mediator realize an actual initial energy density of 344 Wh.kg(-1) and cycle stably for 20 cycles wih a high capacity retention of 88%. This work proposes an effective redox mediator and further verifies the redox mediation strategy for practical high-energy-density Li-S batteries.

Automated summary

This study proposes an effective redox mediator and validates its applicability in high-energy-density Li-S batteries under practical working conditions. By using this mediator, high specific discharge capacity and energy density are achieved, and the battery exhibits good cycling stability.