☆ 4.8 Article

Understanding the structure-performance relationship of active sites at atomic scale

NANO RESEARCH (2022)

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Article Chemistry, Physical

Atomically Dispersed Ni/Cu Dual Sites for Boosting the CO2 Reduction Reaction

Huiyuan Cheng et al.

Summary: This study explores the synthesis of an N-rich carbon matrix with precisely controlled Ni/Cu dual sites through the assistance of metal-organic frameworks, which shows high efficiency and long-term stability in the CO2 reduction reaction.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

Guaiacol Hydrodeoxygenation over Iron-Ceria Catalysts with Platinum Single-Atom Alloy Clusters as a Promoter

Congcong Li et al.

Summary: The study found that Fe/CeO2 catalysts modified with noble metals showed better catalytic performance in guaiacol hydrodeoxygenation reaction compared to unmodified catalysts, and the addition of water contributed to the stability of the catalytic reaction.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

Phosphorus-Driven Electron Delocalization on Edge-Type FeN4 Active Sites for Oxygen Reduction in Acid Medium

Hengbo Yin et al.

Summary: This study demonstrates that incorporating long-range P into FeN4 sites can enhance electron delocalization and significantly improve the catalytic activity for oxygen reduction reaction. The presence of P results in a lower free energy barrier, leading to superior performance in both acidic and alkaline media, showcasing a potential alternative to Pt/C catalysts in fuel cells and batteries.

ACS CATALYSIS (2021)

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Article Materials Science, Multidisciplinary

Pd single-atom monolithic catalyst: Functional 3D structure and unique chemical selectivity in hydrogenation reaction

Zedong Zhang et al.

Summary: The study introduces a simple and practical method to synthesize a monolithic single-atom catalyst supported on nitrogen-doped carbon foams, showing excellent activity and selectivity in semi-hydrogenation reactions. The catalyst's great integrity and mechanical strength allow for easy separation and recycling, demonstrating high reusability and stability. The discovery of isolated site effect offers a new pathway for designing highly selective catalysts, while the development of monolithic single-atom catalysts opens up new opportunities for practical applications.

SCIENCE CHINA-MATERIALS (2021)

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Article Chemistry, Physical

Electronics and coordination engineering of atomic cobalt trapped by oxygen-driven defects for efficient cathode in solar cells

Hongyu Jing et al.

Summary: The rational design and metal coordination environment regulation of single-atom catalysts in specific catalytic reactions are still challenges. Oxygen-defective supports can trap metal species and provide an effective pathway for synthesizing SACs. Density functional theory calculations reveal the importance of intrinsic electronic distributions, electron donating ability, and energy level position in determining the coordination behavior and catalytic performance of SACs.

NANO ENERGY (2021)

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Article Chemistry, Physical

A Highly Efficient Fe-N-C Electrocatalyst with Atomically Dispersed FeN4 Sites for the Oxygen Reduction Reaction

Xinxin Jin et al.

Summary: The study introduces a Fe-N-C electrocatalyst of FeSA/HNPC featuring single-atomic FeN4 sites on hierarchically N-doped porous carbon, which shows competitive ORR activity even at low loading. The FeN4 active sites in FeSA/HNPC existing in the form of pyrrole-N-4-Fe were found to be more favorable for enhanced ORR performance compared to pyridine-N-4-Fe. Understanding the nature of FeN4 active sites will greatly benefit the design of highly effective Fe-N-C electrocatalysts.

CHEMCATCHEM (2021)

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Article Energy & Fuels

Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis

Lichen Bai et al.

Summary: This study presents a general synthesis method for Co-, Fe- and Ni-containing double-atom catalysts from their single-atom precursors via in situ electrochemical transformation. The characterization reveals molecule-like bimetallic active sites for these supported catalysts, with proposed catalytic cycles showing bimetallic cooperation. The mechanisms for O-O bond formation differ in the site and source of OH- as well as the order of proton and electron transfer.

NATURE ENERGY (2021)

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Article Multidisciplinary Sciences

Tunable CO/H2 ratios of electrochemical reduction of CO2 through the Zn-Ln dual atomic catalysts

Zhong Liang et al.

Summary: The study successfully synthesized a series of single and dual atomic catalysts, adjusting the CO/H-2 ratio in the produced syngas. The ZnLa-1/CN catalyst showed good stability and a high faradaic efficiency of up to 80% in producing syngas. Theoretical calculations confirmed the roles of Zn and La in determining CO and H-2 formation, providing a promising strategy for the development of more controllable CO2RR atomic catalysts.

SCIENCE ADVANCES (2021)

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Article Chemistry, Physical

Bimetallic monolayer catalyst breaks the activity-selectivity trade-off on metal particle size for efficient chemoselective hydrogenations

Qiaoqiao Guan et al.

Summary: The precise deposition of a platinum monolayer on large gold nanoparticles breaks the trade-off between activity and selectivity, resulting in high activity and 99% selectivity in the platinum-catalysed hydrogenation of halonitrobenzenes. This breakthrough is attributed to the upshift of the platinum 5d-band centre through platinum lattice expansion and ligand effect, as well as the exposure of more terrace sites on large particles, providing a promising platform for the rational design of metal catalysts with superior performance in hydrogenation reactions.

NATURE CATALYSIS (2021)

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Article Chemistry, Physical

Atomically dispersed iridium on MgO(111) nanosheets catalyses benzene-ethylene coupling towards styrene

Pengxin Liu et al.

Summary: Single-atom catalysis is a frontier of heterogeneous catalysis with potential for efficient metal utilization and unusual reactivity. Understanding the coordination structures of single atoms and developing structure-property relationships remains challenging. Dispersion of Ir(III) species on single-crystalline MgO(111) 2D nanosheets allows for unique reactivity in the coupling of benzene and ethylene, indicating potential for advantageous reactivity scenarios through fine tuning of the interface between single atoms and their supports.

NATURE CATALYSIS (2021)

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Article Multidisciplinary Sciences

Rational strain engineering of single-atom ruthenium on nanoporous MoS2 for highly efficient hydrogen evolution

Kang Jiang et al.

Summary: This study utilizes strain engineering to amplify the synergistic effect between MoS2's sulfur vacancies and single-atom Ru sites, leading to accelerated H-2 evolution electrocatalysis.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

High-Loading Single-Atomic-Site Silver Catalysts with an Ag1-C2N1 Structure Showing Superior Performance for Epoxidation of Styrene

Shubo Tian et al.

Summary: A single-atomic-site Ag catalyst supported by mesoporous graphitic carbon nitride was developed for styrene epoxidation, demonstrating outstanding catalytic performance with high conversion (96%) and selectivity (81%). The catalyst with Ag-1-C2N1 structure showed higher activity and selectivity compared to analogous catalysts, attributed to absorbed superoxide-like O-2 species and lower reaction barrier for styrene oxide generation.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

Matching the kinetics of natural enzymes with a single-atom iron nanozyme

Shufang Ji et al.

Summary: By precisely controlling the electronic structure of the single-atom iron active center, FeN3P-SAzyme exhibits catalytic activity and kinetics comparable to natural enzymes, showing promising potential as an effective therapeutic strategy for inhibiting tumor cell growth.

NATURE CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Low-Temperature Synthesis of Single Palladium Atoms Supported on Defective Hexagonal Boron Nitride Nanosheet for Chemoselective Hydrogenation of Cinnamaldehyde

Zhijun Li et al.

Summary: Metal-support interactions are crucial in determining support-activity in heterogeneous catalysis. A low-temperature synthetic strategy to anchor atomically dispersed palladium atoms on defective h-BN nanosheet was reported. The catalyst demonstrated exceptional efficiency in chemoselective hydrogenation, along with excellent recyclability, sintering-resistant ability, and scalability. The synthetic approach is expected to enable large-scale production of bench-stable catalysts with maximum atom efficiency for industrial applications.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Emerging Dual-Atomic-Site Catalysts for Efficient Energy Catalysis

Weiyu Zhang et al.

Summary: Atomically dispersed metal catalysts with well-defined structures have been a research hotspot in heterogeneous catalysis. Dual-atomic-site catalysts, as an extension of single-atom catalysts, possess higher metal loading and more flexible active sites, offering the potential for better catalytic performance.

ADVANCED MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Rational Design of Single-Atom Site Electrocatalysts: From Theoretical Understandings to Practical Applications

Yao Wang et al.

Summary: This paper systematically summarizes the fundamental understandings and intrinsic mechanisms underlying single-atom site electrocatalysts (SACs) and their electrocatalytic applications, including different preparation strategies and applications. It also discusses in depth the structure-performance relationship between SACs and electrocatalytic reactions, as well as enhancement mechanisms.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Phosphorus Induced Electron Localization of Single Iron Sites for Boosted CO2 Electroreduction Reaction

Xiaohui Sun et al.

Summary: In this study, the introduction of single P atoms was found to enhance the performance of a single Fe atom catalyst in the electrochemical reduction of CO2. Experimental and computational analysis revealed that the presence of single P atoms improved the electronic localization of Fe center, leading to the stabilization of the key *COOH intermediate and enhanced CO2 electrochemical reduction performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Polyoxometalate-Based Metal-Organic Framework as Molecular Sieve for Highly Selective Semi-Hydrogenation of Acetylene on Isolated Single Pd Atom Sites

Yiwei Liu et al.

Summary: By constructing isolated single Pd atom in a polyoxometalate-based metal-organic framework, the selective semi-hydrogenation of acetylene in an ethylene-rich gas stream can be achieved, resulting in a high selectivity of ethylene product.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

An Adjacent Atomic Platinum Site Enables Single-Atom Iron with High Oxygen Reduction Reaction Performance

Ali Han et al.

Summary: The modulation effect can enhance the catalytic activity of Fe-N-4 moiety through adjacent Pt-N-4 moiety, but it is less effective for optimizing the ORR performances of Co-N-4/Pt-N-4 and Mn-N-4/Pt-N-4 systems.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Compressive Strain Modulation of Single Iron Sites on Helical Carbon Support Boosts Electrocatalytic Oxygen Reduction

Jia Yang et al.

Summary: The study demonstrates that strain engineering of curved single atomic iron-nitrogen sites can significantly enhance electrocatalytic activity. The introduction of high-curvature surface with compressive strain on Fe-N-4 sites leads to downshifted d-band center, reducing the bonding strength between oxygenated intermediates and metal sites, resulting in a lower energy barrier for oxygen reduction. Catalytic tests show a 31-fold increase in kinetic current density for curved Fe-N-4 sites compared to planar ones in alkaline media.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

The Electronic Metal-Support Interaction Directing the Design of Single Atomic Site Catalysts: Achieving High Efficiency Towards Hydrogen Evolution

Jiarui Yang et al.

Summary: Catalysts designed by electronic metal-support interactions (EMSI), especially the single atomic site catalyst Rh1-TiC, show higher catalytic efficiency than Pt/C, with smaller overpotentials, lower Tafel slopes, and higher mass activities. Additionally, they demonstrate energy-saving advantages compared to Pt/C.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Tailoring the Local Environment of Platinum in Single-Atom Pt1/CeO2 Catalysts for Robust Low-Temperature CO Oxidation

Dong Jiang et al.

Summary: Tailoring the local environment of isolated Pt2+ by thermal-shock (TS) synthesis leads to a highly active and thermally stable Pt-1/CeO2 catalyst, showing exceptional low-temperature performance in CO oxidation reactions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Atomically Dispersed Pt-N3C1 Sites Enabling Efficient and Selective Electrocatalytic C-C Bond Cleavage in Lignin Models under Ambient Conditions

Tingting Cui et al.

Summary: The study demonstrates a novel electrocatalyst with atomically dispersed Pt-N3C1 sites on nitrogen-doped carbon nanotubes, which shows high activity and selectivity for lignin degradation by cleaving C-alpha-C-beta bonds. This new catalyst achieves exceptional benzaldehyde yield under ambient conditions, opening up opportunities for lignin valorization using a green and sustainable electrochemical route with ultralow noble metal usage.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Creating High Regioselectivity by Electronic Metal-Support Interaction of a Single-Atomic-Site Catalyst

Wen-Hao Li et al.

Summary: By designing and synthesizing a single-atomic-site catalyst with strong electronic metal-support interaction effects, researchers achieved highly selective conversion of electronically unbiased alkynes. Through studying reaction mechanisms, they demonstrated the exciting potential of EMSI in regulating regioselectivity in homogeneous catalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Nanoscience & Nanotechnology

Synergizing metal-support interactions and spatial confinement boosts dynamics of atomic nickel for hydrogenations

Jian Gu et al.

Summary: The synergistic effect of metal-support interactions and spatial confinement enhances the catalytic performance of highly loaded atomic nickel on a graphitic carbon nitride support, leading to improved coke inhibition and outstanding activity in hydrogenation reactions. This approach provides a pathway to design efficient, stable, and highly loaded atomically dispersed catalysts with superior catalytic performance compared to traditional metal nanoparticles.

NATURE NANOTECHNOLOGY (2021)

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Article Nanoscience & Nanotechnology

Copper-catalysed exclusive CO2 to pure formic acid conversion via single-atom alloying

Tingting Zheng et al.

Summary: The single-atom Pb-alloyed Cu catalyst (Pb1Cu) efficiently converts CO2 into formic acid with high selectivity and activity, offering the potential to increase productivity.

NATURE NANOTECHNOLOGY (2021)

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Article Multidisciplinary Sciences

Fabricating polyoxometalates-stabilized single-atom site catalysts in confined space with enhanced activity for alkynes diboration

Yiwei Liu et al.

Summary: Utilizing polyoxometalates-stabilized single-atom site catalysts in confined space supported by MOFs has effectively demonstrated synergistic effects. Pt-1-PMo@MIL-101 exhibits significantly higher activity in the diboration of phenylacetylene compared to nanoparticles, attributed to the preconcentration of organic substrates by porous MOFs skeleton and reduced desorption energy of products on isolated Pt atom sites.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation

Shubo Tian et al.

Summary: The study successfully prepared a mesoporous graphitic carbon nitride-supported dual-atom Pt-2 catalyst, which displayed excellent catalytic performance in the hydrogenation of nitrobenzene to aniline reaction, with a conversion rate higher than that of other comparative catalysts. This catalyst also shows potential applications in other important reactions.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Construction of Pd-Zn dual sites to enhance the performance for ethanol electro-oxidation reaction

Yajun Qiu et al.

Summary: The construction of Pd-Zn dual sites significantly improves the efficiency of ethanol electro-oxidation, exceeding commercial Pd/C by approximately 24 times. Further computational studies reveal that Pd-Zn dual sites promote the adsorption of ethanol and hydroxide ion, optimizing the electro-oxidation pathway.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

Stepping Out of Transition Metals: Activating the Dual Atomic Catalyst through Main Group Elements

Mingzi Sun et al.

Summary: This work explores the potential of using main group elements to create stable dual atomic catalysts based on graphdiyne, showing that the main group elements not only improve the loading of the catalysts but also activate alkyl chains to enhance electroactivity. Furthermore, the involvement of main group elements in the catalysts allows for subtle modulations on electronic structures and does not affect the electroactivity of transition or lanthanide metals.

ADVANCED ENERGY MATERIALS (2021)

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Article Energy & Fuels

Pt/Fe2O3 with Pt-Fe pair sites as a catalyst for oxygen reduction with ultralow Pt loading

Ruijie Gao et al.

Summary: The study focuses on loading platinum onto α-Fe2O3 to create a highly active and stable catalyst with dispersed Pt-Fe pair sites, which exhibits excellent catalytic performance and cycling stability in alkaline conditions.

NATURE ENERGY (2021)

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Article Chemistry, Physical

On the promising performance of single Ta atom in efficient nitrogen fixation

Shuyue Wang et al.

Summary: The electrocatalytic nitrogen reduction reaction (NRR) with atomic Ta catalysts supported by carbon materials was investigated through experiments and theoretical calculations. The Ta-GO catalyst showed higher NRR efficiency, while the Ta-NC catalyst exhibited higher selectivity.

CHEM CATALYSIS (2021)

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Review Materials Science, Multidisciplinary

Bringing catalytic order out of chaos with nitrogen-doped ordered mesoporous carbon

Zhenhui Liu et al.

Summary: Rationally designing an appropriate support is crucial for catalysis, and nitrogen-doped ordered mesoporous carbons (NOMCs) are emerging as intriguing supports with well-defined pore channels and abundant functional groups, offering potential for improved catalysis. Various synthetic strategies can be used to prepare NOMCs, and their applications in electrocatalysis and organic synthesis show promising prospects for future developments.

MATTER (2021)

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Article Materials Science, Multidisciplinary

Strain-controlled single Cr-embedded nitrogen-doped graphene achieves efficient nitrogen reduction

Chao Lin et al.

Summary: This study proposed a new regulation mechanism by applying strain to change the coordination bond length of Cr-N in SACs, enabling quantitative regulation of the electronic state of the active center and achieving an ultra-low over-potential in the NRR. The lattice stretch can adjust the spin-polarization state of the single Cr atom, weakening the adsorption capacity of N-2 and ultimately achieving the desired outcome.

MATERIALS ADVANCES (2021)

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Review Chemistry, Multidisciplinary

Non-carbon-supported single-atom site catalysts for electrocatalysis

Xiaobo Zheng et al.

Summary: This review comprehensively summarizes the recent exciting progress on non-carbon-supported SACs and their applications in electrocatalytic reactions. Eight types of non-carbon-supported SACs are categorized to show their diversity, with detailed analysis of the anchoring and stabilization mechanisms. Advanced characterization techniques for identifying and monitoring the atomic structure of SACs are highlighted, along with discussions on their applications in electrochemical energy conversion.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Physical

Coordination tunes the activity and selectivity of the nitrogen reduction reaction on single-atom iron catalysts: a computational study

Dongxu Jiao et al.

Summary: The coordination structure of Fe-N-C catalyst greatly impacts its catalytic activity towards the nitrogen reduction reaction (NRR), with Fe-B2N2 showing the lowest limiting potential among all B-doped catalysts. Introducing B coordination effectively modulates the interaction of the single Fe atom with N2H* species, enhancing its NRR catalytic performance. Notably, Fe-B2N2 exhibits high NRR selectivity by suppressing the competing hydrogen evolution reaction (HER) both thermodynamically and kinetically.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Physical

Single-Atom Materials: Small Structures Determine Macroproperties

Jiarui Yang et al.

Summary: Single-atom materials (SAMs) have been widely studied in various fields, and their high performance is largely attributed to the microstructure inside the SAM. Achieving the goal of regulating structures and understanding the relationship between macroproperties and small structures are essential but require further efforts in this field. This review comprehensively summarizes and discusses the regulation on microstructures, the characterization of microstructures, and the relationship between macroproperties and small structures, mainly focusing on the application of SAM in catalysts. Proposed challenges and future developments aim to provide an overall view and guidance for future research in this area.

SMALL STRUCTURES (2021)

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Review Chemistry, Physical

Charge Transfer Modulated Activity of Carbon-Based Electrocatalysts

Li Tao et al.

ADVANCED ENERGY MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Synergistically Interactive Pyridinic-N-MoP Sites: Identified Active Centers for Enhanced Hydrogen Evolution in Alkaline Solution

Di Zhao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Physical

Relative Efficacy of Co-X4 Embedded Graphene (X=N, S, B, and P) Electrocatalysts towards Hydrogen Evolution Reaction: Is Nitrogen Really the Best Choice?

Chunjin Ren et al.

CHEMCATCHEM (2020)

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Article Chemistry, Multidisciplinary

Zinc-Mediated Template Synthesis of Fe-N-C Electrocatalysts with Densely Accessible Fe-Nx Active Sites for Efficient Oxygen Reduction

Guangbo Chen et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Edge-Rich Fe-N4 Active Sites in Defective Carbon for Oxygen Reduction Catalysis

Wang Xin et al.

ADVANCED MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Metal-Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction

Xue Feng Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Controlled Synthesis of a Vacancy-Defect Single-Atom Catalyst for Boosting CO2 Electroreduction

Xin Rong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Regulating the Coordination Environment of MOF-Templated Single-Atom Nickel Electrocatalysts for Boosting CO2 Reduction

Yun-Nan Gong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Boosting Oxygen Reduction of Single Iron Active Sites via Geometric and Electronic Engineering: Nitrogen and Phosphorus Dual Coordination

Kai Yuan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

Atomic-level tuning of Co-N-C catalyst for high-performance electrochemical H2O2 production

Euiyeon Jung et al.

NATURE MATERIALS (2020)

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Article Chemistry, Physical

Single-Atom AuI-N3 Site for Acetylene Hydrochlorination Reaction

Zheng Chen et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Tuning Polarity of Cu-O Bond in Heterogeneous Cu Catalyst to Promote Additive-free Hydroboration of Alkynes

Jian Zhang et al.

CHEM (2020)

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Article Nanoscience & Nanotechnology

Surface Hexagonal Pt1Sn1 Intermetallic on Pt Nanoparticles for Selective Propane Dehydrogenation

Chenliang Ye et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Rare-Earth Single Erbium Atoms for Enhanced Photocatalytic CO2 Reduction

Shufang Ji et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Adsorption Site Regulation to Guide Atomic Design of Ni-Ga Catalysts for Acetylene Semi-Hydrogenation

Yueqiang Cao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Improving the Catalytic Activity of Carbon-Supported Single Atom Catalysts by Polynary Metal or Heteroatom Doping

Mengmeng Fan et al.

SMALL (2020)

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Article Chemistry, Multidisciplinary

In Situ Phosphatizing of Triphenylphosphine Encapsulated within Metal-Organic Frameworks to Design Atomic Co1-P1N3 Interfacial Structure for Promoting Catalytic Performance

Jiawei Wan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Materials Science, Multidisciplinary

Coordination structure dominated performance of single-atomic Pt catalyst for anti-Markovnikov hydroboration of alkenes

Qi Xu et al.

SCIENCE CHINA-MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Isolated Ni Atoms Dispersed on Ru Nanosheets: High-Performance Electrocatalysts toward Hydrogen Oxidation Reaction

Junjie Mao et al.

NANO LETTERS (2020)

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Review Chemistry, Physical

Single-atom catalysis enables long-life, high-energy lithium-sulfur batteries

Zechao Zhuang et al.

NANO RESEARCH (2020)

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Article Chemistry, Physical

Fabricating Pd isolated single atom sites on C3N4/rGO for heterogenization of homogeneous catalysis

Ninghua Fu et al.

NANO RESEARCH (2020)

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Article Chemistry, Physical

Synergy of Fe-N4 and non-coordinated boron atoms for highly selective oxidation of amine into nitrile

Hong-Hui Wang et al.

NANO RESEARCH (2020)

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Review Chemistry, Physical

Modulating the local coordination environment of single-atom catalysts for enhanced catalytic performance

Xinyuan Li et al.

NANO RESEARCH (2020)

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Article Energy & Fuels

Tuning nitrogen doping types and pore structures in carbon nanosheets as electrodes for supercapacitor by controlling existence form of iron species

Rui Zhao et al.

JOURNAL OF ENERGY STORAGE (2020)

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Article Chemistry, Physical

Boosting CO2 hydrogenation via size-dependent metal-support interactions in cobalt/ceria-based catalysts

Alexander Parastaev et al.

NATURE CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Gram-Scale Synthesis of High-Loading Single-Atomic-Site Fe Catalysts for Effective Epoxidation of Styrene

Yu Xiong et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Dual Single-Atomic Ni-N4and Fe-N4Sites Constructing Janus Hollow Graphene for Selective Oxygen Electrocatalysis

Jiangyue Chen et al.

ADVANCED MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Single-Atom Alloy Catalysis

Ryan T. Hannagan et al.

CHEMICAL REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Fabricating Dual-Atom Iron Catalysts for Efficient Oxygen Evolution Reaction: A Heteroatom Modulator Approach

Yong-Sheng Wei et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Cross-Linked Polyphosphazene Hollow Nanosphere-Derived N/P-Doped Porous Carbon with Single Nonprecious Metal Atoms for the Oxygen Reduction Reaction

Xuan Wei et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Engineering Isolated Mn-N2C2 Atomic Interface Sites for Efficient Bifunctional Oxygen Reduction and Evolution Reaction

Huishan Shang et al.

NANO LETTERS (2020)

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Article Chemistry, Multidisciplinary

Engineering of Coordination Environment and Multiscale Structure in Single-Site Copper Catalyst for Superior Electrocatalytic Oxygen Reduction

Tingting Sun et al.

NANO LETTERS (2020)

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Article Chemistry, Physical

Controlling N-doping type in carbon to boost single-atom site Cu catalyzed transfer hydrogenation of quinoline

Jian Zhang et al.

NANO RESEARCH (2020)

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Article Chemistry, Physical

Accelerated oxygen reduction on Fe/N/C catalysts derived from precisely-designed ZIF precursors

Ergui Luo et al.

NANO RESEARCH (2020)

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Review Chemistry, Physical

Single-atom site catalysts for environmental catalysis

Ningqiang Zhang et al.

NANO RESEARCH (2020)

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Article Multidisciplinary Sciences

Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity

Huishan Shang et al.

NATURE COMMUNICATIONS (2020)

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Review Chemistry, Multidisciplinary

Single atom alloy: An emerging atomic site material for catalytic applications

Junjie Mao et al.

NANO TODAY (2020)

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Article Chemistry, Physical

Thermal Transformation of Molecular Ni2+-N4 Sites for Enhanced CO2 Electroreduction Activity

Young Jin Sa et al.

ACS CATALYSIS (2020)

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Article Chemistry, Physical

Elucidation of the Active Sites in Single-Atom Pd1/CeO2 Catalysts for Low-Temperature CO Oxidation

Dong Jiang et al.

ACS CATALYSIS (2020)

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Review Chemistry, Multidisciplinary

Single-Atom Catalysts Based on the Metal-Oxide Interaction

Rui Lang et al.

CHEMICAL REVIEWS (2020)

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Review Chemistry, Multidisciplinary

Regulating the coordination structure of metal single atoms for efficient electrocatalytic CO2 reduction

Yuchao Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

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