4.4 Article

Techno-economic analysis of methanol and ammonia co-producing process using CO2 from blast furnace gas

期刊

KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 39, 期 8, 页码 1999-2009

出版社

KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-022-1129-9

关键词

Ammonia Synthesis; Methanol Synthesis; CO2 Utilization; Process Simulation; Techno-economic Analysis; Sensitivity Analysis

资金

  1. National Research Foundation of Korea (NRF) - Korea government (MSIT) [NRF-2021R1F1A106339712]
  2. Regional Innovation Strategy (RIS) through the National Research Foundation of Korea (NRF) - Ministry of Education [2021RIS-003]

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This study proposes two production schemes for methanol production and co-production of methanol and ammonia from blast furnace gas, and evaluates the economics. The results show that the co-production scheme is more economically feasible in terms of net present value (NPV) when the raw material cost decreases by 30%.
In steel manufacturing plants, blast furnace gas is generated from a furnace in which steel ore, coke and limestone are heated and melted. It is commonly used to produce electricity or released to the atmosphere in general; however, it can be utilized as a carbon source to produce C1 value-added chemicals. In this study, we propose two production schemes for methanol production and co-production of methanol and ammonia from blast furnace gas. Both cases were simulated using Aspen Plus V12 and economics was evaluated using Aspen Process Economic Analyzer (APEA). As a result, the methanol production case produced 99.4 wt% 232 t/day of methanol and the co-production case produced 97.7 wt%, 453.4 t/day of ammonia and 99.8 wt%, 263 t/day of methanol. The total annual cost of the methanol production case is US 121.6 M$/y and US 222.1 M$/y at the co-production case. The NPVs are -810.4 M$ in the methanol production case and -981.3 M$ in the co-production case, respectively. By sensitivity analysis, it is shown that the co-production case can be more economically feasible in the aspect of NPV when the raw material cost decreases 30%.

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