期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 -, 期 -, 页码 6342-6348出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.2c01577
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资金
- National Natural Science Foundation of China [51905295, 52075284, 11890672, 51527901]
A long-term lubrication and ultralow friction coefficient are achieved by using PbS quantum dot nanocoating sliding against bearing steel balls in the air through tribo-physchemical interactions. The transfer and structural transformation of nanoparticles form a robust tribo-film, providing a new type of nanolubricant for mechanical engineering.
We report a long-term lubrication for a PbS QD nanocoating sliding against bearing steel balls in the air. Through tribo-physchemical interactions, ultralow friction (mu approximate to 0.078 +/- 0.0026) is achieved for the system tested under 1 N for 60 min. During the rubbing process, the tribo-film of the counterfacing ball is covered by a degraded PbS QD layer and amorphous mixed phase. Meanwhile, the disc track surface is composed of degraded PbS QD steel layers, clustered rearranged PbS QD districts, induced decomposed Pb-enriched multilayers, and an amorphous mixed phase via friction-induced structural transformation. The PbS QDs are transferred onto the sliding contacts to form a robust tribo-film, which is the key to realizing ultralow friction. Consequently, a long-term lubrication mechanism is attributed to the synergetic tribo-physchemical interaction along sliding interfaces upon shift, redirection, and decomposition of nanoparticles. These discoveries reveal QD-based nanolubricants in common working conditions for mechanical engineering.
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