4.6 Article

Metal Oxynitrides for the Electrocatalytic Reduction of Nitrogen to Ammonia

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Nanoscience & Nanotechnology

Electrocatalytic Reduction of Nitrogen to Ammonia: the Roles of Lattice O and N in Reduction at Vanadium Oxynitride Surfaces

Adaeze Osonkie et al.

Summary: Vanadium oxynitride films can reduce both lattice N and dissolved N-2 to NH3 at pH 7, with mechanisms involving oxide-supported V surface sites rather than N-supported sites. Density functional theory calculations support the energetically favored formation of reaction intermediates at oxide-supported V surface sites. Similar effects are predicted for oxynitrides of other oxophilic metals like Ti.

ACS APPLIED MATERIALS & INTERFACES (2022)

Article Chemistry, Physical

Explaining the structure sensitivity of Pt and Rh for aqueous-phase hydrogenation of phenol

Isaiah Barth et al.

Summary: Phenol is an important model compound for understanding the hydrogenation of biomass to biofuels, and the active facets of Pt and Rh catalysts for this reaction have been identified. The study reveals that the activity trends of Pt and Rh nanoparticles in the hydrogenation of phenol are size-dependent, with higher turnover frequencies observed on certain terraces. The increase in experimental turnover frequencies with larger Pt and Rh nanoparticle diameters is attributed to a larger fraction of terraces on the larger particles.

JOURNAL OF CHEMICAL PHYSICS (2022)

Article Multidisciplinary Sciences

Ti2N nitride MXene evokes the Mars-van Krevelen mechanism to achieve high selectivity for nitrogen reduction reaction

Denis Johnson et al.

Summary: This study addresses the issue of low selectivity in the electrochemical nitrogen reduction to ammonia process by utilizing the Mars-van Krevelen mechanism on two-dimensional MXene materials. The results demonstrate that MXene materials can achieve high Faradaic efficiency and yield of NH3. These findings lay the foundation for MXene-based NRR technology.

SCIENTIFIC REPORTS (2022)

Article Materials Science, Multidisciplinary

A first-principles investigation of nitrogen reduction to ammonia on zirconium nitride and oxynitride surfaces

Amitava Banerjee et al.

Summary: This study investigates the electrochemical synthesis of ammonia using density functional theory computation. The research shows that different surface types have a significant impact on the potential-determining step and surface nitrogen vacancy formation is consistently the rate-determining step.

JOURNAL OF MATERIALS SCIENCE (2022)

Article Chemistry, Multidisciplinary

Atomic Molybdenum for Synthesis of Ammonia with 50% Faradic Efficiency

Chenhao Zhang et al.

Summary: In this study, a highly efficient Mo-based NRR electrocatalyst was successfully prepared in acidic electrolytes, with stabilized single Mo atoms anchored on holey nitrogen-doped graphene. Experimental results showed that the electrocatalyst exhibited low overpotentials and exceptional Faradaic efficiency, promoting the catalytic activity of NRR.
Letter Chemistry, Physical

Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction

Jaecheol Choi et al.

NATURE CATALYSIS (2022)

Article Chemistry, Physical

Efficient ambient ammonia synthesis by Lewis acid pair over cobalt single atom catalyst with suppressed proton reduction

Ngoc Quang Tran et al.

Summary: The ammonia yield and Faraday efficiency of ambient electrochemical nitrogen fixation have been improved using a novel catalyst. Positively charged single cobalt atoms anchored on specific nanofibers can suppress unwanted reactions and enhance the conversion of nitrogen. Experimental results confirm the high efficiency of this catalyst.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Multidisciplinary

Atomistic modeling of electrocatalysis: Are we there yet?

Nawras Abidi et al.

Summary: Electrified interfaces play a crucial role in energy technologies, but understanding and modeling them at an atomistic level is challenging due to their structural complexity and the presence of electrochemical potential. Realistic relationships between potential and surface charge require consideration of solvent and counter charge. However, the descriptions of solvent and electrolyte are limited by computational power, leading to validation issues in both explicit and implicit methods.

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2021)

Article Engineering, Environmental

Theory-guided design of nanoporous CuMn alloy for efficient electrocatalytic nitrogen reduction to ammonia

Yuhuan Cui et al.

Summary: In this study, the effect of alloying Cu with Mn on NRR performance was investigated using density functional theory, and it was found that the incorporation of Mn into Cu structure can significantly improve NRR performance. The nanoporous CuMn alloy prepared by dealloying method showed high ammonia yield rate and Faradaic efficiency under ambient conditions, outperforming most reported noble metal catalysts.

CHEMICAL ENGINEERING JOURNAL (2021)

Review Chemistry, Physical

Grand-canonical approaches to understand structures and processes at electrochemical interfaces from an atomistic perspective

Axel Gross

Summary: In electrochemistry, the interface between an electrode and an electrolyte is often influenced by ions from the solution, which can alter the properties of the interface significantly. For electrocatalysis to occur, the reacting species need to come into contact with the surface of the catalyst, highlighting the importance of understanding the interaction between solvated species and electrode surfaces. The determination of resulting adsorbate structures based on electrochemical control parameters is crucial, and theoretical approaches to derive these structures are reviewed with emphasis on the validity of the approach and typical approximations made.

CURRENT OPINION IN ELECTROCHEMISTRY (2021)

Article Chemistry, Physical

A General Strategy to Boost Electrocatalytic Nitrogen Reduction on Perovskite Oxides via the Oxygen Vacancies Derived from A-Site Deficiency

Kaibin Chu et al.

Summary: This study introduces a strategy to enhance NRR activity by modulating oxygen vacancies induced by A-site deficiencies in perovskite oxides. Experimental results show that increasing La-site deficiencies and oxygen vacancies can significantly improve NRR activity, leading to higher NH3 production. The favorable properties of oxygen vacancies include promoting the adsorption/activation of reaction species and optimizing reaction pathways.

ADVANCED ENERGY MATERIALS (2021)

Review Chemistry, Multidisciplinary

Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design

Huidong Shen et al.

Summary: NH3 production currently relies on the energy-intensive Haber-Bosch process, but electrochemical NH3 synthesis powered by renewable electricity offers a promising carbon-neutral and sustainable strategy. However, significant enhancements in energy efficiency, conversion rate, and durability are still needed, achievable only through the design of efficient electrocatalysts.
Review Chemistry, Physical

Roads less traveled: Nitrogen reduction reaction catalyst design strategies for improved selectivity

Bianca M. Ceballos et al.

Summary: This review discusses the necessity of direct electrochemical nitrogen reduction for ammonia production to reduce fossil fuel use, the challenges faced by nitrogen reduction electrocatalysts, and strategies to address these challenges such as catalyst design and reaction conditions control. It also explores some underused approaches for selective catalyst development.

CURRENT OPINION IN ELECTROCHEMISTRY (2021)

Review Materials Science, Multidisciplinary

Layered Double Perovskites

Hayden A. Evans et al.

Summary: The article discusses the successful strategies for designing crystalline materials, focusing on systematically tuning the chemical composition. Perovskites, particularly the layered double perovskites, provide a vast range of functionality through slicing and restacking the perovskite structure with ordered cations and/or anions. The emerging area of hybrid LDPs is particularly rich, leading to exciting discoveries of new compounds with unique structures and fascinating optoelectronic properties.

ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 51, 2021 (2021)

Article Chemistry, Applied

Triggering in-plane defect cluster on MoS2 for accelerated dinitrogen electroreduction to ammonia

Wanru Liao et al.

Summary: A new MoS2 catalyst with in-plane defect clusters was designed for efficient electrochemical nitrogen reduction reaction, achieving high ammonia yield rate and Faradaic efficiency. This work provides a prospecting strategy for fine-tuning in-plane defects in a catalyst and promotes the progress of eNRR.

JOURNAL OF ENERGY CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Unravelling the Reaction Mechanisms of N2 Fixation on Molybdenum Nitride: A Full DFT Study from the Pristine Surface to Heteroatom Anchoring

Youchao Kong et al.

Summary: A comprehensive study was conducted to unravel the reaction mechanisms of N-2 fixation on molybdenum nitride using density functional theory calculations. The Mo and N atoms on the pristine Mo5N6 surface were found to be active for eNRR following different pathways in mechanism, and the catalytic performance could be further boosted by specific metal atom anchoring. A full map of eNRR mechanism on pristine and metal atom-decorated Mo5N6 surfaces was illustrated, offering powerful strategies for the rational design of efficient NRR electrocatalysts.

CHEMSUSCHEM (2021)

Review Chemistry, Inorganic & Nuclear

In situ/operando vibrational spectroscopy for the investigation of advanced nanostructured electrocatalysts

Zhenzhu Xu et al.

Summary: Electrochemical energy conversion through electrocatalysis offers promising solutions to global energy crisis and environmental issues. Understanding the mechanism and structure-activity relationship of key electrocatalytic processes is crucial for designing efficient electrocatalysts. Vibrational spectroscopic methods, such as Raman and FTIR-based techniques, are powerful tools for monitoring surface transformations and reaction intermediates in electrocatalytic processes, attracting attention for future research in this field.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Chemistry, Physical

Understanding the Factors Determining the Faradaic Efficiency and Rate of the Lithium Redox-Mediated N2 Reduction to Ammonia

Pavel Cherepanov et al.

Summary: The study investigated the effects of parameters such as electrode potential, convection, N-2 pressure, and water content on the electrochemical production of ammonia. Results showed that a closely linear ammonia yield and approximately constant faradaic efficiency can be maintained during experiments lasting up to 60 hours. Improved control of reaction conditions led to ammonia yield rates above 1 nmol s(-1) cm(-2) and faradaic efficiencies as high as 60%.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Chemistry, Physical

Electrocatalytic Nitrogen Reduction by Transition Metal Single-Atom Catalysts on Polymeric Carbon Nitride

Mei Zheng et al.

Summary: In this study, the feasibility of transition metal atoms supported on melon-based carbon nitride for electrocatalytic N-2 reduction reaction was systematically studied using first-principles calculations. It was found that single Mo, Ti, or V atom anchored on melon exhibited excellent catalytic activity with low limiting potential and high selectivity towards the eNRR. Furthermore, NH3 desorption was energetically favorable for Mo/melon and V/melon, enhancing their durability for eNRR.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Multidisciplinary Sciences

Methods for nitrogen activation by reduction and oxidation

Haldrian Iriawan et al.

Summary: The article introduces the importance of the industrial Haber-Bosch process for producing ammonia in modern society, discusses the challenges of N-2 activation and the drawbacks of the Haber-Bosch process, proposes new strategies for sustainable N-2 activation, compares the latest research results from different catalytic reactions, and discusses best practices for improving reproducibility and cost-effective methods for rigorous experimentation.

NATURE REVIEWS METHODS PRIMERS (2021)

Article Chemistry, Multidisciplinary

Challenges and opportunities for nitrogen reduction to ammonia on transitional metal nitrides via Mars-van Krevelen mechanism

Zhi Qiao et al.

Summary: Transition metal nitrides are promising catalysts for electrochemical N-2 reduction, but face challenges such as sluggish kinetics and low selectivity. Overcoming these limitations and exploring opportunities for scientific breakthroughs are key for the future of this field.

CELL REPORTS PHYSICAL SCIENCE (2021)

Review Chemistry, Physical

Transition Metal Chalcogenides as a Versatile and Tunable Platform for Catalytic CO2 and N2 Electroreduction

Giorgio Giuffredi et al.

Summary: Transition metal chalcogenides are receiving increasing research interest for their high activity and stability in various electrochemical applications. This review discusses the structural and electronic properties of these compounds in enhancing selectivity and activity towards key reduction reactions such as CO2R and NRR, as well as strategies for future applications. Transition metal chalcogenides have shown promise as catalysts, outperforming many metallic compounds, particularly in the reduction of CO2 to CO and nitrogen fixation.

ACS MATERIALS AU (2021)

Article Chemistry, Multidisciplinary

A Spectroscopic Study of Electrochemical Nitrogen and Nitrate Reduction on Rhodium Surfaces

Yao Yao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Nanoscience & Nanotechnology

Nitride tuning of transition metal perovskites

Amparo Fuertes

APL MATERIALS (2020)

Article Chemistry, Multidisciplinary

Efficient Ammonia Electrosynthesis from Nitrate on Strained Ruthenium Nanoclusters

Jie Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Contribution of Nitrogen Vacancies to Ammonia Synthesis over Metal Nitride Catalysts

Tian-Nan Ye et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

Identification and elimination of false positives in electrochemical nitrogen reduction studies

Jaecheol Choi et al.

NATURE COMMUNICATIONS (2020)

Review Thermodynamics

Advances in electrocatalytic ammonia synthesis under mild conditions

Guoyi Duan et al.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2020)

Article Chemistry, Physical

A vanadium-nickel oxynitride layer for enhanced electrocatalytic nitrogen fixation in neutral media

Bin Chang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Physical

CuO/Graphene Nanocomposite for Nitrogen Reduction Reaction

Fan Wang et al.

CHEMCATCHEM (2019)

Article Chemistry, Physical

Highly efficient electrocatalysts for oxygen reduction reaction: Nitrogen-doped PtNiMo ternary alloys

Lin Luo et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2019)

Article Chemistry, Multidisciplinary

Critical Assessment of the Electrocatalytic Activity of Vanadium and Niobium Nitrides toward Dinitrogen Reduction to Ammonia

Hoang-Long Du et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Multidisciplinary Sciences

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

Suzanne Z. Andersen et al.

NATURE (2019)

Article Chemistry, Multidisciplinary

In Situ Growth of Nitrogen-Doped Carbon-Coated γ-Fe2O3 Nanoparticles on Carbon Fabric for Electrochemical N2 Fixation

Yan Li et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Oxygen Vacancies in Ta2O5 Nanorods for Highly Efficient Electrocatalytic N2 Reduction to NH3 under Ambient Conditions

Wenzhi Fu et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Multidisciplinary Sciences

Doping strain induced bi-Ti3+ pairs for efficient N2 activation and electrocatalytic fixation

Na Cao et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Tuning the Electron Localization of Gold Enables the Control of Nitrogen-to-Ammonia Fixation

Jianyun Zheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium

Hui Cheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Low-Temperature Synthesis of Perovskite Oxynitride-Hydrides as Ammonia Synthesis Catalysts

Masaaki Kitano et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Editorial Material Chemistry, Physical

The Difficulty of Proving Electrochemical Ammonia Synthesis

Jakob Kibsgaard et al.

ACS ENERGY LETTERS (2019)

Article Chemistry, Physical

Challenges in Modeling Electrochemical Reaction Energetics with Polarizable Continuum Models

Joseph A. Gauthier et al.

ACS CATALYSIS (2019)

Review Chemistry, Multidisciplinary

Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf

Antonio Jose Martin et al.

Article Materials Science, Multidisciplinary

Nitrogen Loss and Oxygen Evolution Reaction Activity of Perovskite Oxynitrides

Hassan Ouhbi et al.

ACS MATERIALS LETTERS (2019)

Article Chemistry, Physical

Ambient electrocatalytic nitrogen reduction on a MoO2/graphene hybrid: experimental and DFT studies

Jing Wang et al.

CATALYSIS SCIENCE & TECHNOLOGY (2019)

Article Chemistry, Physical

Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction

Nikifar Lazouski et al.

Article Chemistry, Physical

NiO Nanodots on Graphene for Efficient Electrochemical N2 Reduction to NH3

Ke Chu et al.

ACS APPLIED ENERGY MATERIALS (2019)

Article Chemistry, Physical

NbO2 Electrocatalyst Toward 32% Faradaic Efficiency for N2 Fixation

Linsong Huang et al.

SMALL METHODS (2019)

Article Chemistry, Physical

Efficient electrocatalytic N2 reduction on CoO quantum dots

Ke Chu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Multidisciplinary

Efficient Electrochemical N-2 Reduction to NH3 on MoN Nanosheets Array under Ambient Conditions

Ling Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Multidisciplinary Sciences

A physical catalyst for the electrolysis of nitrogen to ammonia

Yang Song et al.

SCIENCE ADVANCES (2018)

Article Chemistry, Multidisciplinary

Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles

Xuan Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Physical

The stability number as a metric for electrocatalyst stability benchmarking

Simon Geiger et al.

NATURE CATALYSIS (2018)

Editorial Material Chemistry, Physical

Electrochemical Ammonia Synthesis-The Selectivity Challenge

Aayush R. Singh et al.

ACS CATALYSIS (2017)

Review Multidisciplinary Sciences

Perovskites in catalysis and electrocatalysis

Jonathan Hwang et al.

SCIENCE (2017)

Article Chemistry, Applied

Operando X-Ray Photoelectron Spectroscopy Studies of Aqueous Electrocatalytic Systems

Hirohito Ogasawara et al.

TOPICS IN CATALYSIS (2016)

Review Nanoscience & Nanotechnology

Hybrid organic-inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties

Thomas M. Brenner et al.

NATURE REVIEWS MATERIALS (2016)

Article Chemistry, Physical

Nitrogen Activation in a Mars-van Krevelen Mechanism for Ammonia Synthesis on Co3Mo3N

Constantinos D. Zeinalipour-Yazdi et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

Article Chemistry, Physical

Enabling electrochemical reduction of nitrogen to ammonia at ambient conditions through rational catalyst design

Younes Abghoui et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

Review Chemistry, Physical

Review of electrochemical ammonia production technologies and materials

S. Giddey et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)

Article Chemistry, Physical

Chemistry and applications of oxynitride perovskites

Amparo Fuertes

JOURNAL OF MATERIALS CHEMISTRY (2012)

Article Chemistry, Physical

A theoretical evaluation of possible transition metal electro-catalysts for N-2 reduction

Egill Skulason et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

Article Chemistry, Physical

Origin of the overpotential for oxygen reduction at a fuel-cell cathode

JK Norskov et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2004)