Catalytic CO Oxidation by Cu Single Atoms on the UiO-66 Metal-Organic Framework: The Role of the Oxidation State

Recent experiments have demonstrated catalysis by single transition-metal atoms supported on metal-organic frameworks (MOF) but have yet to decipher the role of the transition-metal oxidation state and the reaction mechanism. In this work, we present a study of the aerobic CO oxidation reaction on single Cu atoms supported on the UiO-66 MOF. Characterization of the Cu@UiO-66 catalyst after reduction via infrared spectroscopy of a CO probe molecule reveals the presence of both Cu(I) and Cu(II) oxidation states. Operando infrared spectroscopic experiments further show both oxidation states are also present during reaction, and subsequent mechanistic studies using quantum mechanical calculations have therefore examined the reaction with both Cu(I) and Cu(II). The calculations reveal a variety of different Langmuir-Hinshelwood CO oxidation mechanisms, including those involving coordination of only O2 to Cu at the rate-limiting transition state or both CO and O2. Overall, CO oxidation on Cu(II)@UiO-66 exhibits a lower maximum energetic span than on Cu(I) and is therefore predicted to be faster under operational conditions for most methods examined. The reaction mechanisms for MOF-supported Cu single atoms differ from those involving single-Cu atoms on metal-oxide supports, which opens new avenues for increasingly efficient catalysis.

Automated summary

Recent experiments have studied the catalytic properties of single transition metal atoms supported on metal-organic frameworks (MOF), specifically focusing on the role of transition metal oxidation states and the reaction mechanism. In this study, the aerobic CO oxidation reaction on single Cu atoms supported on UiO-66 MOF was investigated. Experimental characterization and quantum mechanical calculations revealed the presence of both Cu(I) and Cu(II) oxidation states and showed that the CO oxidation reaction can proceed through multiple different mechanisms. The results suggest that CO oxidation on Cu(II)@UiO-66 is predicted to be faster than on Cu(I), indicating the potential for more efficient catalytic processes.