期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.2c03584
关键词
-
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [18K05079]
In this study, a dyad consisting of a modified anthranol with enhanced electron-donating ability and a modified acridine with enhanced electron-accepting ability was found to form crystal polymorphs with different colors and hydrogen-bonding motifs. Structural and spectroscopic analyses revealed that the crystals with unusual colors exhibited stronger intermolecular hydrogen bonding and a red-shifted, enhanced charge-transfer absorption band. The combined experimental and theoretical results suggest a synergistic effect between hydrogen bonding and charge transfer in these crystals.
A dyad comprised of a derivative of anthranol with an improved electrondonating ability and a derivative of acridine having an improved electron-accepting ability was crystal polymorphs, one with a color close to that of the dyad in solution and the other with a completely different color. The polymorphs are comprised of hydrogen-bonded chain aggregates that have different hydrogen-bonding motifs. Structural and spectroscopic analyses showed that the unusually colored crystals possess a stronger intermolecular hydrogen bond. In addition, this crystal displays a charge-transfer (CT) absorption band, corresponding to one-electron transfer from the anthranol unit to the acridine unit, that is red-shifted and enhanced relative to those of the other crystal and the dyad in solution. The combined theoretical and experimental results suggest that hydrogen-bonding and charge-transfer interactions take place synergistically in the unusually colored crystals.
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