期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 17, 页码 11387-11398出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c00890
关键词
-
资金
- CSIR [HCP-23]
- DST-SERB [GAP -2185]
A mild and simple protocol has been developed for the formation of sulfenylated imidazo[1,5-a]pyridines. This metal-free iodine/TBHP-mediated one-pot multicomponent reaction enables C-H functionalization of the imidazo[1,5-a]pyridine skeleton and subsequent sulfenylation to yield the desired products in good to high yields. The extension and applications of this method have also been demonstrated.
A mild and simple protocol has been established for the formation of sulfenylated imidazo[1,5-a]pyridines. This is a metal-free iodine/TBHP-mediated one-pot multicomponent reaction, which follows C-H functionalization of the imidazo[1,5-a]pyridine skeleton formed during the reaction and its subsequent sulfenylation in the same step to offer sulfenylated imidazo[1,5-a]pyridines in good to high yields. The extension and applications of this method have also been demonstrated.
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