期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 17, 页码 11722-11734出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01376
关键词
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资金
- National Science Foundation of China [81573304, 81703342]
- Natural Science Foundation of Jiangsu [BK20211301]
- Natural Science Foundation of Nanjing University of Chinese Medicine [NZY81703342]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX19_1261, SJCX22_0789, KYCX20_1575]
In this study, a novel and efficient synthetic method was developed to construct isoquinolone scaffold and other valuable derivatives through catalytic reaction.
In this study, we report a novel and efficient synthetic method to construct isoquinolone scaffold via the Rh(III)-catalyzed (4 + 2) annulation of benzamide with an unreported coupling reagent methyl 2-chloroacrylate. Accordingly, other valuable 1,2benzothiazine and naphtho[1',2':4,5]imidazo[1,2-a]pyridine derivatives are also obtained through a similar synthetic protocol. Thus, our developed method is highlighted by high yield and reaction versatility.
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