4.6 Article

ZIF-67/rGO/NiPc composite electrode material for high-performance asymmetric supercapacitors

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SPRINGER
DOI: 10.1007/s10854-022-08636-5

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资金

  1. Hebei talent project training funds [A201803003, A202001013]
  2. Program for the Young Top Talents of Hebei Province
  3. Natural Science Foundation of Hebei Province [E2021402004]
  4. Science and Technology Research and Development Projects of Handan City [19422111008-16]

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In this reported study, novel multiple dimensional ZIF-67/rGO/NiPc composite materials were prepared and applied in supercapacitors. The electrochemical test results showed excellent specific capacitance of the composite material electrode at a high current density, and it also exhibited high cyclability. In addition, the asymmetric supercapacitor based on the composite material demonstrated outstanding specific capacitance and energy density.
In this reported study, novel multiple dimensional ZIF-67/rGO/NiPc composite materials were prepared for supercapacitors. The electrochemical test showed that the ZIF-67/rGO/NiPc electrode achieved a remarkable specific capacitance of 860 F g(-1) at a current density of 1 A g(-1), which was superior to that of the rGO/NiPc and ZIF-67/rGO electrodes. An asymmetric supercapacitor based on ZIF-67/rGO/NiPc//activated carbon exhibited a high specific capacitance of 200.67 F g(-1) and an extraordinary energy density of 62.7 Wh kg(-1) at a corresponding power density of 750 W kg(-1). In addition, the device demonstrated 94.6% capacitance retention after 5000 cycles. The assembled asymmetric supercapacitors could easily powered a green light-emitting diode. This work revealed a promising research route for the rational construction of multiple dimensioned high-performance electrodes materials for use in new energy storage devices.

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