期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 115, 期 -, 页码 156-165出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2021.11.034
关键词
Stainless steel; Current collector; Sodium metal anode; Liquid metal; Carbonate electrolyte
资金
- National Natural Science Foundation of China [51972198, 62133007]
- Taishan Scholars Program of Shandong Province [ts20190908, tsqn201812002]
- Natural Science Foundation of Shandong Province [ZR2020JQ19]
- Project of the Taishan Scholar [ts201511004]
The researchers designed a method using a cheap iron substrate and a liquid metal Ga coating to prepare stable and dendrite-free sodium metal anodes. The liquid metal Ga inhibits the growth of sodium dendrites by inducing uniform Na+ flux. Experimental results showed that this method can enhance the efficiency, cycling life, and capacity of batteries.
Metallic sodium (Na) is believed to be a promising anode material for sodium-ion batteries (SIBs) due to its low electrochemical potential, high theoretical specific capacity, superior electrical conductivity, and so on. However, issues such as high chemical activity, the growth of Na dendrites, large volume change, and unstable interface impede its practical application. We design a cheap iron (Fe)-based substrate decorated by a thin liquid metal Ga layer for stable and dendrite-free Na metal anodes in low-cost carbonate electrolytes. The inherent mechanism of Ga-based liquid metal in inhibiting the growth of Na dendrites was revealed for the first time. Liquid metal Ga with sodiophilic property can act as nucleation seeds to decrease the nucleation barrier and induce homogeneous Na+ flux, resulting in uniform and dendrite-free Na deposition. Full cells with Na3V2(PO4)(3) cathode were also assembled to verify the practical application ability of the modified Na metal anode. Under the regulation of the liquid metal layer, the Coulombic efficiency, cycling life, and capacity of batteries are obviously enhanced. The strategy proposed here cannot only reduce the cost of batteries but also improve their electrochemical and safety performance. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据