期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 69, 期 7, 页码 1125-1151出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2016.1170817
关键词
Graphene; metal complex; pi-organometallic; functionalization; cyclopentadienyls; carbonyls
Recent advances in the functionalization of graphene (G) and graphene oxide (GO) using classical coordination complexes, as well as sigma- and -organometallic compounds as precursors, are discussed. Graphene can form hybrids via covalent or non-covalent interactions with metal complexes of carboxylates, amines, polypyridine compounds, a host of N,O-containing ligands, porphyrins, phthalocyanines, carbonyls, cyclopentadienyls, pyrene-containing moieties, and other aromatic structures. The hybrid constructs are interesting for applications in catalysis, energy storage, and corrosion inhibition and present interesting possibilities of modulating the electronic structure of graphene.
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