期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 69, 期 6, 页码 947-956出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2016.1141200
关键词
Hydrothermal synthesis; metal-organic framework; property; coordination polymer
资金
- Department of Education of Liaoning Province [L2015299]
Two isostructural metal-organic frameworks, [ML(H2O)(4)](n) (M = Y(II) (1) and Nd(II) (2)), NaH2L = 5-sulfoisophthalic monosodium salt), have been synthesized by hydrothermal reactions. Each metal is nine-coordinate with a distorted tricapped trigonal prismatic arrangement. L3- is a mu(3) bridge to generate a homometallic 2-D noninterpenetrating (6,3) honeycomb-like topological network structure. The luminescence spectra indicate emission maxima at 406 and 402 nm, respectively. Compounds 1 and 2 show second-harmonic generation responses that are 0.5 and 0.8 times that of urea, respectively. [GRAHICS].
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