期刊
JOURNAL OF COORDINATION CHEMISTRY
卷 70, 期 2, 页码 328-339出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2016.1251588
关键词
Tungsten(VI) complex; oxoperoxo; Schiff base; Fe3O4; magnetic nanoparticles; oxidation; benzyl alcohol
资金
- Research Council of University of Maragheh
- Iran Science Elites Federation (ISEF)
Oxoperoxo tungsten(VI) complex immobilized on Schiff basemodified Fe3O4 super paramagnetic nanoparticles were synthesized and appropriately characterized using FT-IR, XRD, SEM, TEM, EDX, BET, and VSM analysis. The synthesized nanoparticles efficiently catalyzed oxidation of benzylic alcohols with H2O2 as oxidant in high yields, with high to excellent selectivity. The catalyst can be recovered using an external magnetic field and recycled for subsequent oxidation reactions without any appreciable loss of efficiency. The simple preparation, high activity, excellent selectivity, and simple recoverability of the catalyst are advantageous.
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