Synthesis, characterization and X-ray crystal structures of oxidovanadium(V) and dioxidomolybdenum(VI) complexes derived from 2-bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide

Article Chemistry, Inorganic & Nuclear

Syntheses, X-ray crystal structures and catalytic epoxidation of oxidovanadium(V) and dioxidomolybdenum(VI) complexes derived fromN′-(4-Bromo-2-hydroxybenzylidene)benzohydrazide

Qian Wang et al.

Summary: The newly synthesized oxidovanadium and dioxidomolybdenum complexes were characterized by single crystal X-ray diffraction, showing octahedral coordination of V and Mo atoms and the hydrazone ligand acting as a NOO tridentate ligand.

INORGANIC AND NANO-METAL CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Synthesis, characterization, reactivity, and catalytic studies of heterobimetallic vanadium(V) complexes containing hydrazone ligands

Arvind Kumar et al.

Summary: Six heterobimetallic alkali metal dioxidovanadium(V) coordination polymer complexes {[M-6{VO(mu-O)}(2)(mu-OH)(4)(mu(4)-slox/nph)].n DMF}(infinity) were synthesized and characterized, with the structure of one complex determined by X-ray diffraction. These complexes showed strong protein binding affinity and catalytic activity for alcohol oxidation and bromination of organic substrates.

INORGANICA CHIMICA ACTA (2021)

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Article Chemistry, Inorganic & Nuclear

Synthesis, structure, DNA/protein molecular docking and biological studies of hydrazone ligand derived Cu(II) and VO(IV) complexes

Ayyavoo Thirugnanasundar et al.

Summary: Cu(II) and VO(IV) complexes were synthesized and characterized in this study, showing significant antibacterial and antifungal activities as well as strong binding affinities with DNA and protein molecules. The results suggest potential applications in drug development.

INORGANICA CHIMICA ACTA (2021)

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Article Chemistry, Inorganic & Nuclear

Investigation of DNA/BSA binding and cytotoxic properties of new Co(II), Ni(II) and Cu(II) hydrazone complexes

Sivaswamy Kanchanadevi et al.

Summary: Two mononuclear complexes of Co(II) and Ni(II) and a binuclear copper(II) complex were synthesized and characterized for their biological activities, including DNA and protein-binding, antioxidant and anticancer activity. The interaction with DNA and protein, as well as radical scavenging ability, of the complexes were studied, and their cytotoxicity towards human cancer cell lines was tested.

INORGANICA CHIMICA ACTA (2021)

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Article Chemistry, Inorganic & Nuclear

Hydrazone-Based Ligand with Pyrrolidine Donor and Its Molybdenum(VI) Complex: Synthesis, Structure, and Reactivity

Simona Nica et al.

Summary: The Schiff-base condensation of salicylaldehyde and 4-aminobutanehydrazide hydrochloride resulted in a new hydrazone-based ligand H(2)salhyab, which further reacted with bis(acetylacetonato)dioxidomolybdenum to form a new tridentate hydrazone ligand [MoO2(salhycab)(MeOH)], showing efficient catalytic activity in the peroxidic oxidation of phenyl methyl sulfide.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2021)

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Article Chemistry, Multidisciplinary

Dioxomolybdenum(VI) complexes of hydrazone phenolate ligands - syntheses and activities in catalytic oxidation reactions

Md Kamal Hossain et al.

Summary: The new cis-dioxomolybdenum (VI) complexes containing tridentate hydrazone-based ligands have been synthesized and evaluated for their catalytic activities in various oxidation reactions. Complexes 1 and 3 showed better catalytic performances than complex 2 due to the differences in their steric properties.

JOURNAL OF THE INDIAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Inorganic & Nuclear

Synthesis, spectral characterization, SC-XRD, HSA, DFT and catalytic activity of a dioxidomolybdenum complex with aminosalicyl-hydrazone Schiff base ligand: An experimental and theoretical approach

Hadi Kargar et al.

Summary: A new dioxidomolybdenum(VI) complex was successfully prepared and its structure and non-covalent linkages were investigated, validating the distorted octahedral geometry of the complex. The study also explored the catalytic potential of the complex for the selective oxidation of benzylic alcohols to aryl aldehydes.

POLYHEDRON (2021)

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Article Chemistry, Inorganic & Nuclear

The DNA- and protein-binding properties and cytotoxicity of a new copper(II) hydrazone Schiff base complex

Niladri Biswas et al.

Summary: In this study, a novel monomeric copper(II) benzhydrazone complex was synthesized and characterized by various methods. The complex showed potential DNA-binding and protein-binding abilities, as well as promising anticancer activity which was supported by in vitro cytotoxicity assays.

JOURNAL OF COORDINATION CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

In vitro evaluations of biomolecular interactions, antioxidant and anticancer activities of Nickel(II) and Copper(II) complexes with 1:2 coordination of anthracenyl hydrazone ligands

K. S. Neethu et al.

Summary: A series of nickel(II) and copper(II) complexes incorporating anthracenyl hydrazone ligands were synthesized and characterized using spectroscopic techniques. These complexes exhibited strong cytotoxicity towards cancer cells while showing minimal toxicity towards normal cells. The bio-molecular interactions, antioxidant activity, and apoptotic cell death induction of the complexes were also studied, indicating their potential for further research.

INORGANICA CHIMICA ACTA (2021)

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Article Chemistry, Multidisciplinary

A quasilinear hydrazone-based mononuclear dysprosium compound with C4v symmetry exhibiting field-induced complex magnetic relaxation

Peiqiong Chen et al.

Summary: This paper reports a quasilinear hydrazone-based mononuclear dysprosium(iii) compound, which acts as a single-ion magnet with complex magnetic relaxation phenomenon likely associated with single Dy-III ion behavior and short-range intermolecular magnetic dipolar interactions.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Anticancer activity of a new copper(ii) complex with a hydrazone ligand. Structural and spectroscopic characterization, computational simulations and cell mechanistic studies on 2D and 3D breast cancer cell models

Lucia M. Balsa et al.

Summary: The study presents a copper-hydrazone complex with anticancer activity against human breast cancer cells on 2D and 3D models, showing higher efficacy than cisplatin. Molecular docking and dynamics simulations revealed CuHL's interaction with DNA, inducing cell programmed death and genotoxic effects. The compound also decreased breast cancer stem cell population and overcame cisplatin's efficacy on multicellular spheroids.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes with Aroylhydrazone and Ethyl Maltolate Ligands

Dong-Hui Zou et al.

Summary: Two oxidovanadium(V) complexes derived from aroylhydrazones and ethyl maltolate were synthesized and characterized, exhibiting effective olefin epoxidation catalytic activity. The structures of the complexes were confirmed through various analysis methods.

ACTA CHIMICA SLOVENICA (2021)

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Article Chemistry, Multidisciplinary

Synthesis, Crystal Structures, Characterization and Catalytic Property of Copper(II) Complexes Derived from Hydrazone Ligands

Yao Tan et al.

Summary: In this study, two new copper(II) complexes were synthesized and characterized, with X-ray analysis revealing a distorted square pyramidal coordination in complex 1 and an octahedral coordination in complex 2. The catalytic property of these complexes for the epoxidation of styrene was also evaluated.

ACTA CHIMICA SLOVENICA (2021)

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Article Chemistry, Inorganic & Nuclear

Six-coordinated oxidovanadium(V) complexes derived from hydrazone and pyrone ligands: synthesis, spectroscopy, and catalytic property

Ling-Wei Xue et al.

INORGANIC AND NANO-METAL CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Hydrazone complexes of ruthenium(II): Synthesis, crystal structures and catalytic applications in N-alkylation reactions

Kaliyappan Murugan et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2020)

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Article Biochemistry & Molecular Biology

Synthesis, Characterization, Catalytic Activity, and DFT Calculations of Zn(II) Hydrazone Complexes

Temiloluwa T. Adejumo et al.

MOLECULES (2020)

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Article Chemistry, Multidisciplinary

Synthesis, Crystal Structures, Characterization and Catalytic Property of Manganese(II) Complexes Derived from Hydrazone Ligands

Yao Tan

ACTA CHIMICA SLOVENICA (2020)

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Article Chemistry, Multidisciplinary

Synthesis, Crystal Structures and Catalytic Property of Dioxidomolybdenum(VI) Complexes with Tridentate Hydrazones

Xiao-Qiang Luo et al.

ACTA CHIMICA SLOVENICA (2020)

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Article Chemistry, Multidisciplinary

Syntheses, Crystal Structures and Catalytic Property of Oxidovanadium(V) Complexes Derived from Tridentate Hydrazone Ligands

Ya-Jun Cai et al.

ACTA CHIMICA SLOVENICA (2020)

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Article Chemistry, Multidisciplinary

Synthesis, X-Ray Crystal Structure of Oxidovanadium(V) Complex Derived from 4-Bromo-N′-(2-hydroxybenzylidene) benzohydrazide with Catalytic Epoxidation Property

Qi-An Peng et al.

ACTA CHIMICA SLOVENICA (2020)

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Article Chemistry, Multidisciplinary

Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes of N′-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide: Synthesis, Characterization, Crystal Structures and Catalytic Property

Huan-Yu Liu et al.

ACTA CHIMICA SLOVENICA (2020)

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Article Chemistry, Inorganic & Nuclear

New mononuclear dioxidomolybdenum(VI) complexes with hydrazone ligands: Synthesis, crystal structures and catalytic performance

Cong Wang et al.

INORGANICA CHIMICA ACTA (2019)

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Article Chemistry, Inorganic & Nuclear

Syntheses, crystal structures and biological activity of oxidovanadium(V) complexes with tridentate aroylhydrazone ligands

Ya-Li Sang et al.

JOURNAL OF COORDINATION CHEMISTRY (2019)

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Article Chemistry, Inorganic & Nuclear

Synthesis, characterization and single crystal X-ray structures of oxidovanadium(V) complexes derived from N'-(2-hydroxy-3-methoxybenzylidene)-3,5-dimethoxybenzohydrazide with antibacterial activity

Cui-Lin Zhang et al.

JOURNAL OF COORDINATION CHEMISTRY (2019)

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Article Chemistry, Applied

New magnetic supported hydrazone Schiff base dioxomolybdenum (VI) complex: An efficient nanocatalyst for epoxidation of cyclooctene and norbornene

Marzieh Sarkheil et al.

APPLIED ORGANOMETALLIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Synthesis, characterization and crystal structures of vanadium(V) complexes derived from halido-substituted tridentate hydrazone compounds with antimicrobial activity

Ling-Yan He et al.

POLYHEDRON (2018)

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Article Chemistry, Inorganic & Nuclear

Synthesis, Characterization, and Crystal Structures of Dioxomolybdenum(VI) Complexes Derived from Similar Tridentate Hydrazone Compounds with Catalytic Property

H. Y. Liu et al.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Synthesis, crystal structures and catalytic epoxidation properties of dioxomolybdenum(VI) complexes with hydrazone ligands

Yong-Ming Cui et al.

TRANSITION METAL CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Synthesis, crystal structures of oxovanadium(V) complexes with hydrazone ligands and their catalytic performance for the styrene oxidation

Yan Zhang et al.

POLYHEDRON (2017)

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Article Chemistry, Inorganic & Nuclear

Synthesis, crystal structures, and catalytic property of dioxomolybdenum(VI) complexes with hydrazone ligands derived from 3,5-Di-tert-butylsalicylaldehyde

L. Wang et al.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Synthesis, characterization, and crystal structures of dioxomolybdenum(VI) complexes with O,N,N type tridentate hydrazone ligands as catalyst for oxidation of olefins

W. G. Zhang et al.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Catalytic oxidation of olefins and sulfides in the presence of hydrazone-oxidovanadium(V) complex containing VOCl2+ core

Rahman Bikas et al.

INORGANICA CHIMICA ACTA (2016)

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Article Chemistry, Inorganic & Nuclear

Two dioxomolybdenum(VI) complexes with hydrazone ligands: synthesis, characterization, crystal structures and catalytic properties

Dong-Lai Peng

TRANSITION METAL CHEMISTRY (2016)

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Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

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Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

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Article Chemistry, Physical

Immobilization of dioxomolybdenum(VI) complex bearing salicylidene 2-picoloyl hydrazone on chloropropyl functionalized SBA-15: A highly active, selective and reusable catalyst in olefin epoxidation

Mojtaba Bagherzadeh et al.

APPLIED CATALYSIS A-GENERAL (2014)

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Article Chemistry, Multidisciplinary

Dioxomolybdenum(VI) and dioxotungsten(VI) complexes chelated with the ONO tridentate hydrazone ligand: synthesis, structure and catalytic epoxidation activity

Visnja Vrdoljak et al.

NEW JOURNAL OF CHEMISTRY (2014)

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Article Chemistry, Inorganic & Nuclear

Oxidovanadium(V) complexes containing hydrazone based O,N,O-donor ligands: Synthesis, structure, catalytic properties and theoretical calculations

Hassan Hosseini-Monfared et al.

POLYHEDRON (2014)

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Article Chemistry, Inorganic & Nuclear

Dioxomolybdenum(VI) complexes of hydrazones of two substituted salicylaldehydes: synthesis, structures, and catalytic properties

Shao-Bing Ding et al.

JOURNAL OF COORDINATION CHEMISTRY (2013)

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Article Chemistry, Inorganic & Nuclear

Crystal structures of new isostructural oxovanadium(V) complexes with hydrazone ligands

J. Yu

JOURNAL OF STRUCTURAL CHEMISTRY (2013)

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Article Chemistry, Inorganic & Nuclear

Synthesis, characterization, structures, and catalytic property of oxovanadium(V) complexes with hydrazone ligands

N. Wang et al.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY (2013)

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Article Chemistry, Inorganic & Nuclear

Synthesis, structures, and urease inhibitory activities of oxovanadium(V) complexes with Schiff bases

Zhong-Lu You et al.

INORGANICA CHIMICA ACTA (2012)

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Article Chemistry, Inorganic & Nuclear

Syntheses, crystal structures, and catalytic properties of dioxomolybdenum(VI) complexes with hydrazone ligands

Nan-Yan Jin

JOURNAL OF COORDINATION CHEMISTRY (2012)

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Article Chemistry, Physical

A pseudo cubic tetranuclear copper cluster: Synthesis, structure and magnetic property

Ming-Li Liu et al.

JOURNAL OF MOLECULAR STRUCTURE (2012)

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Article Chemistry, Inorganic & Nuclear

Dioxo- and oxovanadium(V) complexes of biomimetic hydrazone ONO and NNS donor ligands: Synthesis, crystal structure and catalytic reactivity

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POLYHEDRON (2011)

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Article Spectroscopy

Spectral studies of copper(II) complexes of tridentate acylhydrazone ligands with heterocyclic compounds as coligands: X-ray crystal structure of one acylhydrazone copper(II) complex

Nancy Mathew et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2011)

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Article Chemistry, Inorganic & Nuclear

Homogeneous green catalysts for olefin oxidation by mono oxovanadium(V) complexes of hydrazone Schiff base ligands

Hassan Hosseini Monfared et al.

INORGANICA CHIMICA ACTA (2010)

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Article Chemistry, Inorganic & Nuclear

Vanadiumoxo-aroylhydrazone complexes: Synthesis, structure and DFT calculations

Hassan Hosseini Monfared et al.

POLYHEDRON (2010)

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Article Chemistry, Multidisciplinary

Synthesis, spectral and structural studies of oxovanadium(IV/V) complexes derived from 2-hydroxyacetophenone-3-hydroxy-2-naphthoylhydrazone: polymorphs of oxovanadium(V) complex [VOL(OCH3)]

M. R. Prathapachandra Kurup et al.

STRUCTURAL CHEMISTRY (2010)

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Article Chemistry, Multidisciplinary

Supramolecular architecture in an oxovanadium(V)-schiff base complex: Synthesis, Ab initio structure determination from X-ray powder diffraction, DNA binding and cleavage activity

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CRYSTAL GROWTH & DESIGN (2007)

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Article Chemistry, Inorganic & Nuclear

Cis di-oxomolybdenum(VI) complexes with a tridentate ONO donor ligand;: synthesis, X-ray crystal structure, spectroscopic properties and oxotransfer chemistry

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TRANSITION METAL CHEMISTRY (2002)

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Vanadium(V) complexes of O,N,O-donor tridentate ligands containing the {V(v)O(OMe)}(2+) unit: Syntheses, structures and properties

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JOURNAL OF COORDINATION CHEMISTRY (2000)

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Synthesis, characterization and X-ray crystal structures of oxidovanadium(V) and dioxidomolybdenum(VI) complexes derived from 2-bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide

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