Investigation of light aromatics removal from industrial wastewater using nano metal organic framework

In this study, the adsorption of benzoic acid and phenols in the aqueous phase by MOF-Cu adsorbent was investigated. A high-performance liquid chromatography (HPLC) device was used to analyze the concentration of contaminants in the solution. Three isotherms, Freundlich, Langmuir, and Temkin were performed for adsorption of Benzoic Acid (BA) and Phenol contaminants. Correlation factor for adsorption isotherms were fitted into Langmuir aqueous BA and Phenol would be 99.89 and 99.98%, respectively. The equilibrium adsorption capacity MOF-Cu of BA and Phenol is 636.73 and 524.42 mg/g, respectively. In this study, high contaminant adsorption with 7C-7C interaction and hydrogen bonding leads to the high capacity of MOF-Cu. In addition, the increase in adsorption capacity of benzoic acid is due to the electronegative property of oxygen in the carbonyl group and the similarity of the carboxylic acid functional group with the adsorbent. The result shows, that at initial time adsorption, has been a non-linear trend. In addition, the first-order kinetic model is not a suitable option for fitting the experimental data of adsorption kinetics and the adsorption kinetics of BA and Phenol is very well compatible with the semi-second order with the correlation Factor being 99.7 and 99.78, respectively. Also, the equilibrium adsorption capacity in pseudo-second order kinetic for BA and Phenol is 613.5 and 523.56 mg/g respectively.

Automated summary

This study investigated the adsorption of benzoic acid and phenols in water by MOF-Cu adsorbent. The concentration of contaminants in the solution was analyzed using high-performance liquid chromatography (HPLC). Three isotherm models, Freundlich, Langmuir, and Temkin, were used to study the adsorption of benzoic acid and phenols. The results showed that MOF-Cu had high adsorption capacity for both benzoic acid and phenols, with an equilibrium adsorption capacity of 636.73 mg/g and 524.42 mg/g, respectively.