期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 620, 期 -, 页码 478-485出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2022.04.018
关键词
Lithium metal batteries; Metal-organic frameworks; MXene; Polymer electrolyte; Flame-retardant
资金
- National Natural Science Foundation of China [52001066, 21805039]
- Natural Science Foundation of Fujian Province [2021J01157]
A polymer composite electrolyte with high ionic conductivity and flame resistance was fabricated by modifying metal-organic framework nanosheets. The modified nanosheets improved the dissociation of lithium salts and enhanced the transportation of ions, as well as strengthened the mechanical and thermal properties.
Though polymer electrolytes have been regarded as promising separators for solid-state lithium metal batteries, their low ionic conductivity, poor thermostability and inflammability limit their practical applications. Herein, a polymer composite electrolyte consisting of metal-organic frameworks modified Ti3C2MXene nanosheets (ZIF-8@MXene) and polymer mixture (PE-ZIF-8@MXene) was fabricated. The fabricated nonflammable ZIF-8@MXene nanosheets have abundant functional groups and Lewis acid sites as well as high specific surface area. In the composite electrolyte, ZIF-8@MXene nanosheets increased the dissociation of lithium salts and provided channels for transporting ions, accelerating the Li ion transportation. They also enhanced the tensile strength, thermostability and flame resistance of PE-ZIF 8@MXene. Consequently, the fabricated flame-retardant PE-ZIF-8@MXene presented high ionic conductivity (4.4 mS cm-1), impressive Li+ transference number (0.76) and enhanced tensile strength (3.77 MPa). In addition, the assembled Li|PE-ZIF-8@MXene|Li had a long cycle life of 2000 h, and Li|PEZIF-8@MXene|LiFePO4 batteries displayed a capacity retention of 89.6% after 500 cycles.
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