Ultra-thin carbon bridged MoC quantum dots/g-C3N4 with charge-transfer-reaction highways for boosting photocatalytic hydrogen production

Constructing heterojunction has been proved to be an efficient strategy for enhancing the photocatalytic performance of g-C3N4 by prohibiting charge recombination and providing surface active sites. Herein, a novel structure of ultra-thin carbon bridged MoC quantum dots/g-C3N4 nanosheets was constructed for the first time to facilitate carrier transfer and accelerate surface reactions. In our designed composites, a surface-to-surface contact has been formed between conductive carbon layer and g-C3N4 nanosheet via ultrasonic assembly process. Moreover, there exist strong interfaces between MoC QDs and carbon layer because of the in-situ conversion method. As to this unique structure, the ultra-thin carbon layer functions as charge separation and migration high ways while the MoC QDs perform as noble-metal-free co-catalysts consuming the surface electrons promptly. Significantly, an optimal 40 wt% MoC QDs-C/g-C3N4 photocatalyst (MCCN) is synthesized with a hydrogen evolution rate of 2989 mu mol h(-1) g(-1), which is 69.6 and 1.7 times higher than that of pure g-C3N4 and Pt/g-C3N4, respectively. Our work provides new insights on designing highly efficient heterojunction photocatalysts for water splitting.(c) 2022 Published by Elsevier B.V.

Automated summary

The construction of a novel structure of ultra-thin carbon bridged MoC quantum dots/g-C3N4 nanosheets has been achieved for the first time, facilitating carrier transfer and accelerating surface reactions. The designed composites feature a surface-to-surface contact between a conductive carbon layer and g-C3N4 nanosheet, as well as strong interfaces between MoC QDs and the carbon layer. The ultra-thin carbon layer serves as charge separation and migration pathways, while the MoC QDs act as noble-metal-free co-catalysts consuming surface electrons. The optimal MCCN photocatalyst exhibits significantly higher hydrogen evolution rate than pure g-C3N4 and Pt/g-C3N4.