4.3 Article

Composition dependence of structural and piezoelectric properties in Bi(Mg0.5Ti0.5)O3-modified BaTiO3-BiFeO3 ceramics

期刊

JAPANESE JOURNAL OF APPLIED PHYSICS
卷 61, 期 SN, 页码 -

出版社

IOP Publishing Ltd
DOI: 10.35848/1347-4065/ac85c7

关键词

BiFeO3; -based ceramics; Lead-free piezoelectric ceramics; Relaxor ferroelectrics

资金

  1. Graduate Program for Power Energy Professionals, Waseda University, of the Japanese Ministry of Education, Culture, Sports, Science, and Technology (MEXT) WISE Program

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This study investigated the chemical composition dependence of Bi(Mg0.5Ti0.5)O-3 (BMT)-modified BaTiO3 (BT)-BiFeO3 (BF) ceramics fabricated by solid-state synthesis. The research showed that controlling the BT/BF ratios and BMT concentration can alter the crystal structure and piezoelectric properties, making the ceramics potential candidate materials for various practical applications.
The chemical composition dependence of the Bi(Mg0.5Ti0.5)O-3 (BMT)-modified BaTiO3 (BT)-BiFeO3 (BF) ceramics fabricated by a solid-state synthesis was studied. The effects of BT/BF ratios and BMT concentration on the crystal structure, piezoelectric, and ferroelectric properties were investigated. The crystal structure study carried out under the synchrotron radiation X-ray diffraction revealed a change from rhombohedral structure to the pseudo-cubic structure when the BT contents were increased. A significant change in crystal structure and piezoelectric characteristics was confirmed by varying the BT/BF ratios. In contrast, the crystal symmetry remained unaffected by varying the BMT concentration, while tailoring of the piezoelectric and ferroelectric properties was revealed. Based on the analysis of the structural characteristics and overall electrical properties, the ceramics with modification of the BMT content along with BT/BF ratios could be applied as candidate materials for various practical applications.

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