期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 47, 期 65, 页码 28034-28045出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.06.120
关键词
Hydrogen storage; LOHC; Chemical kinetics; Chemical equilibrium
This paper aims to provide a comprehensive and reliable model for the catalytic hydrogenation and dehydrogenation of liquid organic hydrogen carriers (LOHCs). The study takes into account the occurrence of high-temperature phenomena and introduces two novel modifications to make the model applicable over a wide temperature range.
Liquid organic hydrogen carriers (LOHCs) are drawing interest as a viable storage technology because of many favourable characteristics, such as high gravimetric and volumetric energy density. However, technological readiness is still limited, and very few kinetic and thermodynamic models are currently available. This paper aims to provide a complete and reliable model for the catalytic hydrogenation and dehydrogenation of a 0H-NEC/12H-NEC system following a general chemical thermodynamics approach that could easily extend to other LOHCs. The insurgence of already documented high-temperature phenomena has been taken into account by introducing two novel modifications to the base model, making the model reliable over a wide temperature range. First, the model identifies a maximum rate constant reached for a threshold temperature; secondly, it evaluates thermodynamic equilibrium conditions to account for a maximum H-2 uptake. (C) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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