期刊
INORGANIC CHEMISTRY
卷 61, 期 32, 页码 12828-12834出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c01912
关键词
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资金
- National Natural Science Foundation of China [22001061, 22171246, U1804253]
- Key Science and Technology Project of Henan Province [21A150023]
- China Postdoctoral Science Foundation [2020M682309]
- High Performance Computing Center of Henan Normal University
This article reports a new boron compound and its synthesis and application research. The formation mechanism of the compound was elucidated through experimental and theoretical studies, and the molecular structure was illustrated for the first time. In addition, another boron compound was successfully synthesized using this compound as a starting material.
The design, synthesis, and applications of new boranes are eternal topics in boron chemistry. A new bis(borane)alkanethiolate salt, K[BH3S(CH3)BH3], was synthesized in high yield by the reaction of K with (CH3)(2)SmiddotBH(3) at room temperature. The formation mechanism was elucidated based on experimental and theoretical studies. The single-crystal structure of the K[BH3S(CH3)BH3]middot18-crown-6 adduct was determined in which the B-S-B bonding information of K[BH3S(CH3)BH3] was illustrated for the first time. Using K[BH3S(CH3)BH3] as a starting material, KB3H8 was successfully synthesized.
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