期刊
INORGANIC CHEMISTRY
卷 61, 期 25, 页码 9595-9604出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c00930
关键词
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资金
- Baylor University
- Welch Foundation [AA-1846]
- National Science Foundation [1753025]
- Australian Research Council [FT16010007, DP20010013]
Borole-doped polycyclic aromatic hydrocarbons (PAHs) have been synthesized and studied in this work. Intermolecular nitrene and oxygen atom insertion reactions were used to access 1,2-azaborine- and 1,2-oxaborine-containing analogues. Iodosobenzene was established as a versatile reagent for oxygen atom insertion reactions into various borole species to access 1,2-oxaborine systems.
Borole-doped polycyclic aromatic hydrocarbons (PAHs) have garnered attention in recent years due to their attractive photophysical properties and potential utility in electronic devices. In this work, a borole-doped PAH, 12-boradibenzofluorene, is synthesized and formal intermolecular nitrene and oxygen atom insertion reactions were employed to access 1,2-azaborine- and 1,2-oxaborine-containing analogues of the carbonaceous PAH pentaphene. Iodosobenzene is established as a versatile reagent for oxygen atom insertion reactions into a variety of borole species to access 1,2-oxaborine systems.
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