期刊
JOURNAL OF COMPOSITE MATERIALS
卷 50, 期 27, 页码 3843-3852出版社
SAGE PUBLICATIONS LTD
DOI: 10.1177/0021998315626258
关键词
Metal-matrix composites; boron carbide; particle dispersion; interface reaction; reactive wetting
资金
- China Nuclear Power Engineering Co., Ltd. [2013966003]
Microstructure evolution of 15wt% boron carbide particle reinforced aluminum matrix composites (B4C/Al composites) with titanium addition during liquid-stirring process was dynamically characterized in this paper. B4C particles were rapidly dispersed under the mechanical stirring. Many B4C clusters were formed in the melt before 20min, but gradually scattered in matrix beyond 20min, owing to further reactive wetting through interface reaction in addition to stirring. After rapid improvement, distribution uniformity slowly approached to completely uniform distribution during 20-55min, even better than random distribution at 55min. Interface reaction produced Al3BC, TiB2, and AlB2 by B4C erosion and Al3Ti decomposition; however, AlB2 only precipitated in matrix after long time stirring. The growth of TiB2 transformed from a fine layer to discretely coarse crystals on the B4C surface. Reaction mechanism and relationship between reactive wetting and particle dispersion were discussed.
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