期刊
FUEL
卷 319, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2022.123846
关键词
Modified zeolite molecular sieve; HC catcher; Cold-start; HC emission control; Adsorption simulation
资金
- National Natural Science Foundation of China [52006058, 51776062]
- Natural Science Foundation of Hunan Province, China [2020JJ5071]
This study numerically investigated the adsorption process of modified zeolites utilized in hydrocarbon catcher for hydrocarbon emission control during cold-start. The results showed that different types of zeolite have different adsorption effects on different hydrocarbon molecules under different conditions.
To discover adsorbents with promising adsorption capability for hydrocarbon catcher, this study numerically investigated the adsorption process of modified MOR, MFI, and CON zeolites utilized in hydrocarbon catcher of hydrocarbon (HC) molecules for hydrocarbon emission control during cold-start. Ethylene (C2H4) and benzene (C6H6) were used as probe molecules in the single-component adsorption simulation. The mixture of methane (CH4), C2H4, propylene (C3H6), propane (C3H8), water (H2O) and C6H6 was used as adsorbate in the multi component adsorption simulation. The Grand Canonical Monte Carlo (MC) method was used in the adsorption simulation. Grey Relational Analysis (GRA) method was used to determine the influence degree of zeolite molecular sieve type and environmental conditions on the adsorption capacity of hydrocarbons. The adsorption isotherms of hydrocarbon single component and multicomponent molecules on different silicon-aluminum (Si/ Al) ratios and different ion exchange zeolites were studied at various low temperatures and pressures. Results of adsorption simulation present that the best adsorption effect on C(2)H(4)was obtained for the magnesium ion (Mg2+) modified MFI molecular sieve at a Si/Al ratio of 3. The adsorption of C6H6 was better for the Na+ modified molecular sieve at Si/Al ratios of 15 and 7. Mg2+ modified MOR molecular sieve can be given priority when the overall control of hydrocarbon mixture content is required, which has adsorption for all kinds of hydrocarbon molecules and more uniform adsorption performance. The calcium ion (Ca2+) modified MFI molecular sieve is suitable for the condition when exhaust gas contains more C3H6, while Mg2+ modified MFI molecular sieve can be used when there are more C3H8. In GRA, the factors with the greatest influence on the adsorption of the C(2)H(4)component are the type of molecular sieve and the porosity. The most important factors on the adsorption of the C6H6 component are the molecular sieve type and temperature, followed by the porosity. In the adsorption of multicomponent hydrocarbons, porosity has the greatest effect on the adsorption amount, followed by molecular sieve type and Si/Al ratio. In addition, the total adsorption of hydrocarbon molecules will be increased with the Si/Al ratio of the molecular sieve.
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