期刊
FOOD CHEMISTRY
卷 382, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2022.132359
关键词
Metabolomics; Phenolic compounds; Harvest season; Chemical stability; PLS-DA; Chemometrics
资金
- Embrapa [SEG 03.13.06.008.00.00]
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [314737/2018-9, 310586/2018-6]
- Fundacao de Amparo a Pesquisa do Estado da Bahia (FAPESB) [BOL0789/2017]
- Fundacao Cearense de Apoio ao Desenvolvimento Cientifico e Tecnologico (FUNCAP) [NT-00159-00006.01.00/19]
The study evaluated the impact of grape maturity and maceration time on the chemical composition of wines, as well as their chemical stability. It was found that wines made from unripe grapes had higher levels of phenolic acids and short-chain organic acids, while wines from overripe grapes had increased levels of proanthocyanidins and flavonoids. Stable wines were produced from overripe grapes containing more galacturonic acid.
Touriga Nacional is a well-adapted Portuguese grape variety in Sao Francisco River Valley (northeastern Brazil). Nevertheless, it has only been indicated to short-term consumption because of the lack of chemical stability, which is attributed to low grape acidity and incomplete phenolic maturity. Therefore, we used Ultra-Performance Liquid Chromatography coupled High-resolution Mass Spectrometry, Nuclear Magnetic Resonance and chemometrics (PCA and PLS-DA) to evaluate the grape maturity and maceration time on chemical composition of wines from two harvest seasons. Moreover, we investigated how these experimental factors could affect their chemical stability. Grapes maturity showed to be the main effect. Overall, phenolic acids and short-chain organic acids were found to be at higher levels in wines produced with unripe grapes from February and shorter maceration time (p < 0.05). Proanthocyanidins and other flavonoids were increased in wines macerated for longer time using overripe grapes harvested in July. Furthermore, stable wines were made from overripe grapes, which contained more galacturonic acid.
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