期刊
ADVANCED FUNCTIONAL MATERIALS
卷 25, 期 25, 页码 3847-3854出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201500587
关键词
boronic acid functionality; cis-diol moieties; linker fragmentation; metal-organic frameworks; reversible binding
类别
资金
- Natural Science Foundation of China [51072053, 51372084, 51132009]
- Innovation Program of Shanghai Municipal Education Commission [13zz040]
- Nano-Special Foundation for Shanghai Committee of Science and Technology [12nm0502600]
- 111 Project [B14018]
Introduction of accessible boronic acid functionality into metal-organic frameworks (MOFs) might to endow them with desired properties for potential applications in recognition and isolation of cis-diol containing biomolecules (CDBs). However, no investigation is found to address this topic until now. Herein, Cr-based MOFs of MIL-100 (MIL stands for Materials from Institut Lavoisier) integrated with different pendent boronic acid group (MIL-100-B) are reported. This new functional material is successfully prepared using a simple metal-ligand-fragment coassembly (MLFC) strategy with isostructure to the parent MIL-100 as verified by X-ray diffraction characterization. The integration and content tunability of the boronic acid group in the framework are confirmed by X-ray photoelectron spectroscopy and B-11 NMR. Transmission electron microscopy reveals that MIL-100-B can evolve into well-defined morphology and nanoscale size at optimized boronic acid incorporating level. The obtained MOFs exhibit comparable surface areas and pore volumes with parent MIL-100 and present exceptional chemical stability in a wide pH range. The inherent boronic acid components in MIL-100-B can effectively serve as the recognition units for the cis-diol moieties and consequently enhance the capture capabilities for CDBs. The exceptional chemical stability, high porosity, and good reusability as well as the intrinsic cis-diol moieties recognition function prefigure great potential of the current MIL-100-B in CDBs purification, sensing, and separation applications.
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