期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2022, 期 31, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202200770
关键词
Diversity-oriented; Organic semiconductor; Perylene bisimide; Soluble precursor; Sulfur extrusion
资金
- JSPS KAKENHI, Japan [JP20H05863, JP20K15257, JP20H05867, JP22K14663]
- JST, PRESTO, Japan [JPMJPR21Q7]
- Shorai Foundation for Science and Technology
- Research Foundation for the Electrotechnology of Chubu
- Mitsui Chemicals (Mitsui Chemicals Award in Synthetic Organic Chemistry, Japan)
Preparation of organic semiconductors by solution processes is desirable for flexible electronic devices. Our group reported new soluble precursors that can be transformed into n-type organic semiconductors through heating or light-irradiation. We developed a second-generation synthetic route to enable large-scale and diverse preparation of various N-substituted DNTBIs and identified suitable combinations of leaving group, external stimulus, and N-substituent for efficient charge transport.
Preparation of organic semiconductors by solution processes is desirable to create flexible electronic devices. The use of soluble precursors, which exhibit high solubility in common organic solvents and afford the corresponding semiconducting molecules upon appropriate external stimuli such as heat and light, is a promising approach to realize this goal. Our group recently reported new soluble precursors, namely dinaphtho[1,8-bc:1 ',8 '-ef]thiepine bisimide (DNTBI) and its sulfoxide, which afforded perylene bisimide, a representative n-type organic semiconductor, upon heating or light-irradiation. In this work, we report the second-generation synthetic route to DNTBI, which enabled gram-scale and diversity-oriented preparation of various N-substituted DNTBIs. We also disclosed the suitable combination of leaving group (S or SO), external stimulus (heat or light), and N-substituent to realize efficient charge transport.
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