Simultaneous removal of dissolved sulphide and dissolved methane from anaerobic effluents with hollow fibre membrane contactors

Dissolved gases in the effluent of anaerobic reactors, specifically dissolved methane (D-CH4) and sulphide (S2-), are a drawback for anaerobic-based sewage treatment plants (STPs). This article studied the simultaneous desorption/removal of both gases from anaerobic effluents with hollow fibre membrane contactors (HFMCs), evaluating two types of membrane materials (e.g. microporous and dense) at different operating conditions (atmospheric air as sweeping gas or vacuum, and different gas/liquid flows and vacuum pressures). The transfer of other gases, such as O-2 and CO2, was studied as well. Desorption/removal efficiencies up to 99% for D-CH4 and 100% for S2- were obtained, with the higher efficiencies reported for the dense HFMC and with air as sweeping gas. It was found that the removal mechanism for S2- was oxidation with O-2 from the air. In addition, the use of air as sweeping gas allowed the obtention of a nearly O-2 saturated effluent, with more elevated dissolved oxygen concentrations in the microporous HFMC. Finally, it was found that the higher mass-transfer resistance in the dense membrane was compensated by a better performance in the liquid phase (lower mass-transfer resistance) in this unit, which allowed better D-CH4 desorption efficiencies.

Automated summary

This article studied the simultaneous desorption/removal of dissolved methane and sulphide from anaerobic effluents with hollow fibre membrane contactors. The results showed that using dense membrane and air as sweeping gas resulted in higher removal efficiencies, and the removal mechanism for sulphide was oxidation with oxygen from the air. In addition, using air as sweeping gas increased the dissolved oxygen concentration in the effluent.