4.7 Review

Recent Advances in the Development of Metal-Organic Frameworks for Propylene and Propane Separation

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Covalent-Linking-Enabled Superior Compatibility of ZIF-8 Hybrid Membrane for Efficient Propylene Separation

Ziyang Wang et al.

Summary: A covalent-linking strategy was used to enhance the interface compatibility of a ZIF-8-based membrane for propylene separation. The resulting ZIF-8-CN@tPIM-1 membrane showed significantly improved propylene permeation property and selectivity, with high C3H6 permeability.

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A new yttrium-based metal-organic framework for molecular sieving of propane from propylene with high propylene capacity

Shi Tu et al.

Summary: A new yttrium-based ultramicroporous metal-organic framework was designed for molecular sieving separation of C3H6 from C3H8, showing high adsorption capacity and excellent separation performance.

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Control of intracrystalline diffusion in a bilayered metal-organic framework for efficient kinetic separation of propylene from propane

Qi Ding et al.

Summary: This study reports the high-efficient kinetic separation of propylene (C3H6) and propane (C3H8) in a bilayered metal-organic framework Zn-ATA. By manipulating intracrystalline diffusion and surface permeation, the material achieves quasi-molecular-sieving kinetic separation with a selectivity 50 times higher than nanometric Zn-ATA crystals. The breakthrough results set a new benchmark for kinetic C3H6/C3H8 separation.

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Separation of propylene and propane with pillar-layer metal-organic frameworks by exploiting thermodynamic-kinetic synergetic effect

Yongwei Chen et al.

Summary: Efficient separation of C3H6 and C3H8 was achieved using metal-organic frameworks with strong binding sites for C3H6 and hindered diffusion for C3H8.

CHEMICAL ENGINEERING JOURNAL (2022)

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Design and prediction of metal organic framework-based mixed matrix membranes for CO2 capture via machine learning

Jian Guan et al.

Summary: This study applies machine learning to the development of mixed matrix membranes based on metal organic frameworks, achieving improved CO2 separation performance.

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Efficient Separation of Propylene from Propane in an Ultramicroporous Cyanide-Based Compound with Open Metal Sites

Yi Xie et al.

Summary: The newly developed ultramicroporous material nickel nitroprusside (Ni-NP) demonstrates high efficiency in separating propylene from propane at ambient conditions, with high selectivity and absorption capacity for C3H6/C3H8 separation. The material can be easily obtained through a simple precipitation reaction under ambient conditions, highlighting its potential for scale-up production.

SMALL STRUCTURES (2022)

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Separation of propylene and propane with a microporous metal-organic framework via equilibrium-kinetic synergetic effect

Qi Ding et al.

Summary: The efficient separation of propylene and propane in a phosphate anion-functionalized metal-organic framework was achieved by a synergetic effect of equilibrium and kinetics, offering excellent thermodynamic and kinetic selectivity for C3H6/C3H8 separation. This breakthrough method demonstrates outstanding separation capability and easy regeneration, marking the first observation of equilibrium and kinetics cooperative C3H6/C3H8 adsorption separation in anion-functionalized MOFs.

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M-gallate MOF/6FDA-polyimide mixed-matrix membranes for C2H4/C2H6 separation

Guining Chen et al.

Summary: Mixed-matrix membranes (MMMs) incorporating M-gallate (M = Ni, Co, Mg) MOF particles were fabricated using 6FDA-based polyimides for ethylene/ethane separation. Among the different MOF particles, Ni-gallate(F) showed the best compatibility with the polyimide, resulting in improved C2H4/C2H6 selectivity and permeability.

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Rapid Screening of Metal-Organic Frameworks for Propane/Propylene Separation by Synergizing Molecular Simulation and Machine Learning

Hongjian Tang et al.

Summary: In this study, a hierarchical approach combining molecular simulation and machine learning was developed to rapidly screen for the best metal-organic frameworks for propane/propylene separation. The study successfully identified new MOFs with superior separation performance compared to the top-performing known materials.

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Customized H-bonding acceptor and aperture chemistry within a metal-organic framework for efficient C3H6/C3H8 separation

Peng Hu et al.

Summary: This study reported an efficient method for separating propylene/propane through cooperative equilibrium-kinetic synergetic effect in a nodes-engineered Zr-MOF scaffold. By adjusting aperture chemistry and microenvironment, excellent separation performance for C3H6 and C3H8 was achieved, providing a new approach for gas separation research.

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MOF-in-COF molecular sieving membrane for selective hydrogen separation

Hongwei Fan et al.

Summary: COFs are promising for separation membranes, but MOF-in-COF membranes show significant enhancement in hydrogen selectivity over other gases.

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Tuning the gating energy barrier of metal-organic framework for molecular sieving

Xue-Wen Zhang et al.

Summary: The study demonstrates that gating action can be used for molecular sieving and gas separation. By adding amino groups to the metal-organic framework, the gating energy barrier is increased, enhancing the selectivity of CO2/N2 and CO2/CH4. Different pressures for pore opening induced by C2 and C3 hydrocarbons allow for molecular sieving of C2H4/C2H6 and C3H6/C3H8.
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Defect Engineering in Metal-Organic Frameworks Towards Advanced Mixed Matrix Membranes for Efficient Propylene/Propane Separation

Tae Hoon Lee et al.

Summary: A novel strategy of defect engineering in MOFs improves the performance of MMMs, enhancing C3H6 permeability and C3H6/C3H8 selectivity. The study reveals that defect sites in MOFs provide ultrafast diffusion pathways for MMMs and facilitate C3H6 sorption.

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Pore Distortion in a Metal-Organic Framework for Regulated Separation of Propane and Propylene

Liang Yu et al.

Summary: Regulated separation of propylene and propane was achieved in a metal-organic framework by designed pore distortion, demonstrating high selectivity and large capacity. In situ neutron powder diffraction and inelastic neutron scattering provided insights into the binding domains of adsorbed propylene molecules and host-guest interaction dynamics in HIAM-301. This study sets a new benchmark for the adsorptive separation of propylene and propane.

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Machine Learning Meets with Metal Organic Frameworks for Gas Storage and Separation

Cigdem Altintas et al.

Summary: The acceleration in design of new metal organic frameworks (MOFs) has led scientists to focus on high-throughput computational screening (HTCS) methods. Recent implementation of machine learning (ML) to HTCS of MOFs has been fruitful for revealing hidden structure-performance relationships and understanding performance trends in different applications, specifically for gas storage and separation.

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Wiggling Mesopores Kinetically Amplify the Adsorptive Separation of Propylene/Propane

Ya-Fei Yuan et al.

Summary: A highly efficient adsorptive separation technology was achieved by creating wiggling mesopores in carbon materials, allowing for effective separation of propylene and propane with similar properties. The resulting material demonstrated remarkable selectivity and stability, surpassing both existing carbon adsorbents and competitive crystalline porous adsorbents.

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Squarate-Calcium Metal-Organic Framework for Molecular Sieving of CO2 from Flue Gas with High Water Vapor Resistance

Rui Tu et al.

Summary: This study targeted a squarate-calcium metal-organic framework with strong water stability for CO2 extraction from flue gas. The framework showed excellent separation performance for CO2/N2 with high adsorption selectivity values and strong interaction with CO2, making it a promising adsorbent for CO2 removal in practical applications.

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Orthogonal-array dynamic molecular sieving of propylene/propane mixtures

Heng Zeng et al.

Summary: Metal-organic frameworks (MOFs) are known for their precise control of structures and functions on a molecular level, but designing local flexibility in the MOF framework for dynamic molecular sieving remains challenging. A newly reported MOF material, JNU-3a, features one-dimension channels with embedded molecular pockets that can selectively adsorb propylene and propane under different pressures, showcasing the potential of dynamic molecular sieving.

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Electrochemical synthesis of continuous metal-organic framework membranes for separation of hydrocarbons

Sheng Zhou et al.

Summary: Metal-organic framework membranes fabricated using an electrochemical method show potential for energy-efficient separation of hydrocarbons, with the ability to enhance both total flux and separation selectivity under high pressures. This membrane-based approach offers a cost-effective method for various separation processes.

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A novel mechanism of controlling ultramicropore size in carbons at sub-angstrom level for molecular sieving of propylene/propane mixtures

Shengjun Du et al.

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